中文摘要：

合成了邻菲啰啉合高氯酸根配离子,并用X-射线单晶衍射方法对其进行了晶体结构解析,结果表明,该化合物为三斜晶系,晶胞为P-1,晶胞参数:a=0.73397(11),b=1.3202(2),c=2.2382(3)nm,V=2.0934(5)nm3,Z=4,Mr=460.87,Dc=1.462g/cm3,T=298(2)K,F(000)=952,μ(MoKα)=0.091cm-1,R=0.0675和wR=0.1770,化合物分子通过分子间氢键和π-π堆积作用形成了一维链状结构。

英文摘要：

Bis(1-H-1,10-phenanthroline)-bis(1,10-phenanthroline)-bis(perchloate) was synthesized in CH3CH2OH solvent.The crystal structure of bis(1-H-1,10-phenanthroline)-bis(1,10-phenanthroline)-bis(perchloate) has been determined by X-ray single crystal diffraction.The result shows it is triclinic,P-1,a=0.73397(11),b=1.3202(2),c=2.2382(3) nm,V=2.0934(5) nm3,Z=4,Mr=460.87,Dc=1.462 g/cm3,T=298(2) K,F(000)=952,μ(Mo Kα)=0.091 cm-1,R=0.0675 and wR=0.1770.The compound formed 1D chained structure through intermolecule hydr...