通过室内试验模拟沉积物在不同频率下的悬浮过程,研究了悬浮频率对颗粒态磷生物有效性的影响.结果表明,沉积物悬浮导致颗粒态磷的生物有效性显著降低,30d时,藻类可利用态磷(AAP)占悬浮物总磷(Tot-P)的百分比仅为初始状态(56.75%)时的26.24%(悬浮频率较小)和20.04%(悬浮频率较大).内源磷形态分析表明,尽管悬浮物中铁铝结合态磷(Fe/Al-P)含量呈增加的趋势,但非闭蓄态Fe/Al-P(即AAP)占Fe/Al-P的比重却明显降低.这主要与沉积物悬浮导致溶解氧融入(溶解氧从初始状态时的3mg.L-1增至试验结束时的6mg.L-1)和pH值改变(pH值从初始状态时的8.02分别降至7.80(悬浮频率较小)和7.60(悬浮频率较大))有关.沉积物悬浮导致水体中可被利用颗粒态磷(BAPP)和溶解态磷(DTP)含量降低,从而导致上覆水中生物有效磷(BAP)含量降低.
Lab-scale experiments were conducted to investigate the effect of sediment resuspension under different frequency conditions on bio-availability of particulate phosphorus(PP) in the overlying water.The results show that the bio-availability of PP decreased obviously under sediment resuspension conditions,compared with the initial state.After 30 d,the percentages of algal available phosphorus(AAP) to total phosphorus(Tot-P) in suspended solids were 26.24%(lower frequency) and 20.04%(higher frequency) of the initial state(56.75%),respectively.Sequential fractionation indicated that the proportions of non-occluded Fe/Al-P(AAP) to Fe/Al-P decreased gradually under sediment resuspension conditions with time increasing,although the concentrations of Fe/Al-P increased markedly in suspended solids.This was attributed to dissolved oxygen(DO) penetration and pH values change.Under sediment resuspension conditions,DO concentrations increased from 3 mg.L-1(initial state) to 6 mg.L-1(the end).In addition,pH values decreased from 8.02(initial state) to 7.80(lower frequency) and 7.60(higher frequency),respectively.The concentrations of bio-available particulate phosphorus(BAPP) and dissolved total phosphorus(DTP) reduced under sediment resuspension conditions.Correspondingly,the content of bio-available phosphorus(BAP) decreased in the overlying water,compared with the initial state.