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底泥加入铁盐对水体磷的吸收和固定
  • ISSN号:0254-6108
  • 期刊名称:环境化学
  • 时间:2013.5.5
  • 页码:797-802
  • 分类:X524[环境科学与工程—环境工程]
  • 作者机构:[1]苏州科技学院环境科学与工程学院,苏州215011
  • 相关基金:国家自然科学基金项目(51178284,50938005,51278523,50908154)资助
  • 相关项目:城市水体复合污染的表观污染效应及其控制
中文摘要:

对加入FeCl3的底泥在扰动条件下对外源磷的吸收效果进行研究,并通过内源磷数量分布分析了固定效果.磷吸附等温线结果表明,对FeCl3质量百分比占2%的底泥而言,磷吸附最大值、磷平衡浓度、磷饱和度分别为未加入FeCl3的原底泥的273%、85.7%、60.7%.磷吸附实验结果表明,加入FeCl3的底泥对上覆水中磷的吸收能力增加.FeCl3质量百分比占1%和2%的底泥对外源磷的吸收量分别为未加入FeCl3的原底泥的150%和210%,而达到饱和时间也分别从17 d延长至26 d和35 d.内源磷的主要分布为Fe/Al-P(57.1%—63.4%)、HCl-P(19.9%—28.4%)、NH4Cl-P(12.9%—15.2%).由于FeCl3的加入抑制了Fe/Al-P向HCl-P的转化,加入的外源磷主要形成了藻类可利用磷(AAP).

英文摘要:

Phosphorus adsorption was investigated by sediments with ferric chloride addition under sediment disturbance conditions and phosphorus immobility was analyzed by the distribution of sedimentary phosphorus forms. Phosphorus adsorption isotherm results show that phosphorus adsorption maximum, equilibrium solution phosphorus concentration and phosphorus saturation in the sediments with 2% ferric chloride addition were 273%, 85.7% and 60. 6% of that in the sediments without ferric chloride addition. The increase of phosphorus adsorption by sediments with ferric chloride addition was observed in the experiments. The accumulative adsorption of external phosphorus by the sediments with 1% and 2% ferric chloride addition was 150% and 210% of that in the sediments without ferric chloride addition. In addition, the time of phosphorus saturation extended from 17 d (without ferric chloride addition) to 26 d (1% ferric chloride addition) and 35 d (2% ferric chloride addition ), respectively. The rank order of sedimentary phosphorus forms was Fe/A1-P ( 57. 1%---63.4%) , HC1-P (19.9%--28.4%) and NH4C1-P ( 12. 9%--15.2%). The incorporated phosphorus into sediments accorded mainly algae available phosphorus. The main reason is that the transformation from Fe/A1-P to HC1-P might be inhibited due to ferric chloride addition.

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期刊信息
  • 《环境化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:郭良宏
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjhx@rcees.ac.cn
  • 电话:010-62923569
  • 国际标准刊号:ISSN:0254-6108
  • 国内统一刊号:ISSN:11-1844/X
  • 邮发代号:82-394
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27127