采用反应溅射法制备以GdO。或Gd0N为存储层的MONOS(Metal—Oxide—Nitride—Oxide—Si)电容存储器,研究了GdO。中氧含量以及掺氮对MONOS存储器存储特性的影响。实验结果表明,含氧气氛中制备的GdO其氧空位(电荷陷阱)较少,且界面处存在较多Gd—Si键,导致界面态密度增加,因而存储特性欠佳;引入氮至GdO中可诱导出大量的深能级电子陷阱,并能提高介电常数、减少界面缺陷,因此GdON样品表现出好的存储特性:较大的存储窗口(±13v/1s的编程/擦除电压下,存储窗口4.1V)、高的工作速度、好的保持特性以及优良的疲劳特性(105循环编程/擦除后,存储窗口几乎不变)。
The MONOS (Metal-Oxide-Nitride-Oxide-Si) capacitor memory with GdOx or GdON as charge storage layer (CSL) is fabricated by the reactive sputtering method, and the in- fluences of different oxygen content and nitrogen incorporation in CSL on the MONOS memory characteristics are investigated. Experimental resuhs show that GdO CSL prepared in oxygen-rich ambient has less oxygen vacancies (charge traps) and many Gd-Si bonds near the interface, lead- ing to its poor interface quality and memory characteristics. The incorporation of nitrogen in GdO CSL induces a large number of deep-level electron traps, increases its dielectric constant and de- creases the interface traps, so that the sample with GdON as CSL exhibits excellent memory characteristics, i.e. a large memory window of 4.1 V (at ± 13 V, 1 s), high operating speed, good retention properties and the excellent endurance properties (after 10SP/E cycles, the memo- ry window almost remains unchanged).