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中文摘要：
围绕我国生态安全和地下水资源保护的重大需求，针对目前国内外 POPs 研究现状，本项目计划运用多种微观观测手段（包括1H NMR、13C NMR、FTIR、X-射线衍射(XRD)、扫描电子显微镜(SEM)、原子力显微镜(AFM)、动态光散射等），结合宏观实验和模型分析，采用环境科学和环境工程多领域交叉研究的方法，发展POPs 环境行为定量化研究的方法学，系统研究POPs 的结构、土壤及胶体的结构性质对POPs 吸附/解吸行为的影响、土壤生物过程及非生物过程对POPs 降解作用及其影响因素、POPs 随不同物化性质胶体向地下水的运移特性以及POPs 在地下水含水层的迁移规律。阐明POPs 在土壤中的重要环境过程机制，定量评估给定土壤环境条件下POPs 对地下水的影响，为POPs 的控制和生态风险评估提供理论指导和科学依据。
结论摘要：
英文主题词persistent organic pollutants; sorption;biodegradation; chemical degradation; colloid-enhanced transport
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