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有机合成化学与方法学
  • 项目名称：有机合成化学与方法学
  • 项目类别：创新研究群体科学基金
  • 批准号：20821062
  • 申请代码：B020101
  • 项目来源：国家自然科学基金
  • 研究期限：2009-01-01-2011-12-31
  • 项目负责人：席振峰
  • 负责人职称：教授
  • 依托单位：北京大学
  • 批准年度：2008
中文摘要：

北京大学"有机合成化学与方法学"创新研究群体充分发挥整体与个体的双重优势，将科研工作集中在有机合成化学与方法学的国际前沿和主流方向上，在有机合成新反应、新方法、物理有机和理论有机化学、以及功能性复杂有机化合物的合成化学三个领域深入、系统地开展了工作，圆满完成预期计划，取得了一批创新研究成果。近六年来，本群体成员作为通讯作者共在该项目的研究中标注发表SCI论文340余篇（2009年以来第二期发表论文205篇），其中（括号中数字表示2009年以来第二期发表论文数）Acc. Chem. Res. 3篇（3篇），J. Am. Chem. Soc. 44篇（22篇），Angew. Chem. Int. Ed. 23篇（17篇），Adv. Mater. 4篇（2篇），Nat. Chem. 1篇（1篇），Chem. Eur. J. 18篇（12篇）， Chem. Commun. 23篇（19篇），Chem. Rev. 1篇（1篇），Chem. Soc. Rev. 3篇（2篇）；本群体成员应邀在国内外重要学术会议上做大会报告或邀请报告110余次。

中文主题词：
成果综合统计
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  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
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期刊论文
A Concise Approach for the Total Synthesis of Pseudolaric Acid A
Facile One-Pot Construction of Polycyclic Frameworks using a Synergistic Diels–Alder Reaction, Ene R
Diastereoselective Addition of Lithium Enolate of gama-Substituted alpha- Diazoacetoacetate to N-Sul
Rh(II)-Catalyzed Reaction of alpha–Diazocarbonyl Compounds bearing beta-Trichloroacetylamino Substit
Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Telluri
LiCl-Promoted Pd(II)-catalyzed ortho carbonylation of N,N-dimethylbenzylamines
Au(PPh3)Cl–AgSbF6-catalyzed rearrangement of propargylic1,3-dithianes: formation of 8-membered 1,3-b
A Solution Process for Size-Controlled Growth and Transfer of Organic Nanostructures with Manufactur
Chromophore-functionalized dendrimers for sensing applications,Frontiers of Chemistry in China
Conjugated Diene Assisted Allylic C-H Bond Activation: Cationic Rh(I) Catalyzed Syntheses of Polysub
Rh(I)-Catalyzed Two-Component [(5+2)+1] Cycloaddition Approach toward [5-8-5] Ring Systems
Construction of All-Carbon Quaternary Center by R2AlCl?Mediated Ring-Opening Reaction of Oxacycles
Ruthenium-Catalyzed Nucleophilic Allylic Substitution Reactions from β-Silylated Allylic Carbonates
Density Functional Theory Study of the Mechanism and Origins of Stereoselectivity in the Asymmetric
One-pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available
Structural-Property Relationship in Pyrazino[2,3-g]quinoxaline Derivatives: Morphology, Photophysic
Ln4(CH2)4-Cubane-Type Rare-Earth Methylidene Complexes Consisting of “(C5Me4SiMe3)LnCH2” Units (Ln =
Organopalladium(IV) Chemistry
Pd-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones or Diazoesters with Terminal Alkynes: A N
a,b-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselectiv
Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One
Catalytic Thia-Sommelet-Hauser Rearrangement: Application to the Synthesis of Indolin-2-ones
Palladium-Catalyzed C—C Bonds Formation Reactions via Selective C—H Bonds Functionalization
Carbon-Carbon Formation via Ni-Catalyzed Suzuki-Miyaura Coupling through C-CN Bond Cleavage of Aryl
Cross Dehydrogenative Arylation (CDA) of a Benzylic C-H Bond with Arenes by Iron Catalysis
Formal total synthesis of (±)-hirsutic acid C using the tandem Rh(I)-catalyzed [(5+2)+1] cycloadditi
Development of New Stereodiverse Diaminocyclitols as Inhibitors of Influenza Virus Neuraminidase
Rh(I)-Catalyzed Intramolecular [3+2] Cycloadditions of 1-Ene-, 1-Yne- and 1-Allene-Vinylcyclopanes
Reaction of α-ene-Vinylcyclopropanes: Type-II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddit
Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne-/1-Ene-Vinylcyclopropanes and CO: A Homologous Paus
Mechanisms of the Thermal Cyclotrimerizations of Fluoro- and Chloro-Acetylenes: DFT Investigation an
Palladium-Catalyzed, One-Pot, Three-Component Approach to alpha-Alkynyl Indoles from o-Bromo-(2,2-di
Silyl-substituted 1,3-Butadienes for Diels–Alder Reaction, Ene Reaction and Allylation Reaction
Challenge and Progress: Palladium-Catalyzed sp3 C-H Activation
Bromination-Mediated Regioselective Preparation of Cyclopentadienyl-Type [60]Fullerene Derivatives w
协同效应：双金属有机化合物及Lewis酸促进的金属有机化学反应
An unprecedented silver salt effect switches the facial selectivity in the vinylogous Mukaiyama aldo
A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Cat
Preparation of Ketolactone and Bislactone [60]Fullerene Derivatives and Their Conversion into Open-C
New Insights into the Torquoselectivity of Staudinger Reaction
Star-Shaped Donor-π-Acceptor Conjugated Molecules: Synthesis, Properties, and Modification of Their
Pd-Catalyzed C=C Double Bond Formation by Coupling of N-Tosylhydrazones with Benzyl Halides
Highly Enantioselective Hydrogenation of Quinolines Using Phosphine-Free Chiral Cationic Ruthenium C
Facile Synthesis of Isomerically Pure Fullerenols and Formation of Spherical Aggregates from C-60(OH
High-Performance Organic Field-Effect Transistors from Organic Single-Crystal Microribbons Formed by
Formal Total Synthesis of N-Methylmaysenine
Zn(OTf)2-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpred
Selective synthesis of dibenzo[a,c]cyclooctatetraenes via palladium-catalyzed [4+4] cyclic homocoupl
Opening the Silole Ring: Efficient and Specific Cleavage of the endo-C(sp2)-Si Bond with AcOH/ROH Sy
Zirconocene and Si-Tethered Diynes: A Happy Match Directed toward Organometallic Chemistry and Organ
Preparation of Open-Cage Fullerenes and Incorporation of Small Molecules Through Their Orifices
Gold(I)-Catalyzed Ring Expansions of Unactivated Alkynylcyclopropanes to (E)-2-Alkylidenecyclobutana
Solution-Processable Flower-Shaped Hierarchical Structures: Self-Assembly,Formation, and State Trans
Efficient One-pot Synthesis of N-Containing Heterocycles by Multi-Component Coupling of Silicon-teth
Dierct C-H Transformation via Iron Catalysis
Phosphine and Water Cocatalyzed [3+2] Cycloaddition Reactions of 2-Methyl-2,3-butadienoate with Fuma
High-Performance Air-Stable Organic Field-Effect Transistors: Isoindigo-Based Conjugated Polymers
AuPPh3Cl/AgOTf-Catalyzed Reaction of Terminal Alkynes: Nucleophilic Addition to Activated C=O Bond
An unexpected palladium migration from vinylic sp2 carbon to allylic sp3 carbon,
Iterative Dianion Relay Along the Ring: Formation of gem-Bis(trimethylsilyl) Cyclopentenones from 2,
Exploration of new C-O electrophiles in cross-coupling reactions
Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard
Synthesis of Decahydropyrrolo[2,1,5-cd]indolizine through Consecutive [2 + 3] Cycloadditions and 6-E
Aceno[2,1,3]thiadiazoles for Field-Effect Transistors: Synthesis and Crystal Packing
Skeletal rearrangement of all-carbon spiro skeletons mediated by Lewis acid
Ruthenium Catalysts for Structurally Controlled Mono- and Bis-Allylation ofActive Methylene Compound
Asymmetric Total Synthesis and Structural Elucidation of NFAT-68
Transition-Metal-Catalyzed C–C Bond Formation through the Fixation of Carbon Dioxide
Star-Shaped Oligo(fluorene ethynylene)-Functionalized Truxene Derivatives: Synthesis, Characterizati
Diastereoselective Total Synthesis of (±)-Schindilactone?A
Copper-free cycloaddition of azide and alkyne in crystalline state facilitated by arene-perfluoroar
Rh-Catalyzed [7+1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooc
A DFT Study of the Mechanisms and Stereochemistry of the Rh(I)-Catalyzed Intramolecular [3+2] Cycloa
Synthesis of Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open Ether Moieties throug
Gold(I)-Catalyzed Cycloisomerization of Enynes Containing Cyclopropenes,
InI3- or ZnI2-Catalyzed Reaction of Hydroxylated 1,5-Allenynes with Thiols: a New Access to 3,5-Disu
Formation of Zirconocenes Containing Vinyl-imine and Keteniminate Species from Zirconacycles and Dip
Carving two adjacent holes on [60]fullerene through two consecutive epoxide to diol to dione transfo
Coupling of N-Tosylhydrazones with Terminal Alkynes: Synthesis of Trisubstituted Allenes
Diazotization/Cross-Coupling of Anilines with Arylboronic Acids
p-Conjugated Dendrimers as Stable Pure-Blue Emissive Materials: Photophysical, Electrochemical, and
Direct Imidation to Construct 1H-Benzo[d]imidazole through PdII-Catalyzed C-H Activation Promoted by
Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C-O Bond Activati
Pd-catalyzed coupling of beta-hydroxy alpha-diazocarbonyl compounds with aryl iodides: a migratory i
Alkyl Aluminum Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substitute
Oxidative dimerization of N-protected and free indole derivatives toward 3,3'-biindoles via Pd-catal
Ir-Catalyzed Highly Selective Addition of Pyridyl C–H Bonds to Aldehydes Promoted by Triethylsilane
Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed C-O Activation
Organo-di-lithio Reagents: Reaction and Synthetic Applications
Why Is Copper(I) Complex More Competent Than Dirhodium(II) Complex in Catalytic Asymmetric O?H Inser
Palladium-Catalyzed Cross-Coupling of Aryliodide with ?-Trimethylsiloxy ?-Diazoesters: Novel Approac
Gold(I)-catalyzed arylmethylation of terminal alkynes
Arylation and Vinylation of alpha-Diazocarbonyl Compounds with Boroxines
Efficient Cage-Opening Cascade Process for the Preparation of Water-Encapsulated [60]Fullerene Deri
One-Dimensional Microwires Formed by the Co-Assembly of ComplementaryAromatic Donors and Acceptors
Au-catalyzed isomerization of cyclopropenes: a novel approach to indene derivatives
Fullerenyl azide: synthesis and reactivity
Synthesis and Reactivity of 2H-Pyran Moiety in [60]Fullerene Cage Skeleton
Switchable Open-Cage Fullerene for Water Encapsulation
Surface Modification of Self-Assembled One-Dimensional Organic Structures:White-Light Emission and B
Benzo[e]isoindole-1,3-diones as Potential Inhibitors of Glycogen Synthase Kinase-3 (GSK-3). Synthesi
Recent Progress in Pd-Catalyzed Reactions of Diazo Compounds
Pd-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones with Arylboronic Acids
Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Squence
Palladiun-Catalyzed Coupling Reaction of α-Diazocarbonyl Compounds with Aromatic Boronic Acids and H
The Chemistry of Open-cage Fullerene, Hydroxylamine Mediated Hole-closing and -opening Reactions
Construction of Polysubstituted Olefins through Ni-Catalyzed Direct Activation of Alkenyl C-O of Sub
Solution-Processed, High-Performance Nanoribbon Transistors Based on Dithioperylene
Recent Progress on Organic and Polymeric Electrochromic Materials
On the Mechanism of the Palladium Catalyzed Intramolecular Pauson?Khand-Type Reaction
Unexpected Regioselectivity in the Synthesis of Pyranonaphthoquinone via the Diels?Alder Reaction
Direct functionalization of benzylic C–Hs with vinyl acetates via Fe-catalysis
Asymmetric Total Synthesis of Caribenol A
Total Synthesis of (±) Maoecrystal V
An efficient organocatalytic method for constructing biaryls through aromatic C-H activation
Highly Fluorescent Rigid Supramolecular Polymeric Nanowires Constructed Through Multiple Hydrogen Bo
CdSe/ZnS Nanoparticle Composites with Amine-Functionalized Polyfluorene Derivatives for Polymeric Li
Benzothiadiazole-Based D-π-A-π-D Organic Dyes with Tunable Band Gap: Synthesis and Photophysical Pr
Star-shaped Silacyclobutene-Containing π-Systems: Synthesis and Optical Properties
硅杂六元环化合物的反应
硅杂六元环化合物的合成
硅杂四元环化合物的合成和反应
Direct Conversion of Arylamines to the Pinacol Boronates: A Metal-Free Borylation Process
Synthesis of fullerene multiadducts with mixed oxygen and nitrogen addends including five secondary
Assembly of Janus Fullerol: a novel approach to prepare rich carbon structures
Pd-Catalyzed Three-Component Coupling of N-Tosylhydrazone, Terminal Alkyne, and Aryl Halide
Rh(I)-catalyzed carbonylative carbocyclization of tethered ene- and yne-cyclopropenes
Gold(III)-Catalyzed Halogenation of Aromatic Boronates with N-Halosuccinimides
Palladium-Catalyzed Direct Cyanation of Indoles with K4[Fe(CN)6]
A Piezochromic Luminescent Complex: Mechanical Force Induced Patterning with a High Contrast Ratio
Cationic Iridium Dendrimers: Synthesis and Photophysical Properties
TfOH-Catalyzed Tandem Cyclopropane Ring Enlargement/C-C Formation/Etherification of Alkynylcycloprop
Enantioselective Rhodium-Catalyzed Allylic C-H Activation/Addition to Conjugated Dienes
Advances in the Synthesis and Reactivity of 2-Pyranylidene Carbene Complexes
金属杂六元环的合成方法研究进展,
Formation of α-Lithio Siloles from Silylated 1,4-Dilithio-1,3-butadienes: Mechanism and Applications
Isolation and X-ray Structure of a Trimeric 1,4-Dilithio-1, 3-butadiene and a Dimeric Me3Si-substitu
Microwave-Assisted, Pd(0)-Catalyzed Cross-Coupling of Diazirines with Aryl Halides
Polycyclic Imide Derivatives: Synthesis and Effective Tuning of Lowest Unoccupied Molecular Orbital
CuBr-Catalyzed Coupling of N-Tosylhydra zones and Terminal Alkynes: Synthesis of Benzofurans and Ind
Recent Development in Pd-Catalyzed Reaction of Diazo Compounds
Ru(II)-Catalyzed Rearrangement of 2-Aryl-2-(phenylthio)penta-3,4-dienyl 2,2,2-trichloroacetimidate
Single Organic Microtwist with Tunable Pitch
Electrospun Nanofibrous Film Doped with a Conjugated Polymer for DNT Fluorescence Sensor
Formal Synthesis of Cortistatins
Neocuproine-KOtBu Promoted Intramolecular Cross Coupling to Approach Fused Rings
Mutual Activation: Suzuki-Miyaura Coupling through Direct Cleavage of the sp2 C-O Bond of Naphtholat
Arylation of Alfa-Pivaloxyl Ketones with Arylboronic Reagents via Ni-Catalyzed sp3 C-O Activation
Direct Sequential C-O and C-C Formation via Double sp2 C-H Bond Activations to Construct 6H-Benzo[c]
Benzothiadiazole Containing D-π-A Conjugated Compounds for Dye-Sensitized Solar Cells: Synthesis, Pr
New Fused Heteroarenes for High-Performance Field-Effect Transistors
基于钯催化的C—H键选择性官能团化构建C—C键
γ-取代的α-重氮β-羰基酯化合物的烯醇锂盐对N-亚磺酰亚胺的高度非对映选择性加成
Diastereoselective addition of lithium enolate of γ-substituted α-diazoacetoacetate to N-sulfinyl imines
钯催化重氮化合物反应的研究进展
Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement
席振峰的项目
第二届中日青年有机化学研讨会
阳离子性过渡金属杂环化合物的合成及应用
期刊论文 3
第七届国际华人有机化学会议
第十三届全国金属有机化学学术讨论会
基于羰基碳氧双键选择性切断的合成化学新反应新方法
期刊论文 22
氮杂半瞬烯合成、结构与反应
第一届金属有机化学与催化国际学术研讨会
　过渡金属促进的利用二氧化碳作为碳源的新型碳－碳键形成反应
基于金属促进的化学键活化的有机合成方法学研究
期刊论文 101
有机双锂试剂分子内化学键切断反应、机理与应用
期刊论文 25
第21届国际金属有机化学大会
　主族金属有机化合物的反应化学
　双金属有机合成试剂的发现与发展
有机磷化学
主族与稀土活性金属有机化合物的合成、分离与应用
　主族金属有机化合物的反应化学
中国国家自然科学基金委员会—荷兰皇家艺术与科学院第二届
期刊论文 1
新型双/多金属试剂（物种）
期刊论文 1
第八届国际华人有机化学研讨会暨第五届国际华人无机化学研讨会
第二届Tateshina国际有机化学会议
有机合成化学与方法学
期刊论文 147 会议论文 19 获奖 22
The 20th International Conference on Organometallic Chemistry
Tetrahedron Symposium 2010
金属促进的非活性化学键的选择性切断与应用
期刊论文 70
　双铜有机合成试剂的合成与应用
期刊论文 67
稀土双金属有机合成试剂的研究及应用
期刊论文 17 会议论文 9
双金属有机合成试剂研究
期刊论文 2
　双金属有机合成试剂的合成与应用