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中文摘要：
选择与腐殖酸有相似芳香结构的有机物进行氯化试验，测定其卤乙酸及三卤甲烷生成量，研究前体物化学结构与氯化消毒副产物生成特性的关系．结果表明：①主要卤乙酸生成活性排序为：对羟基苯甲酸〉4-氨基苯乙酮〉邻苯二酚〉间苯二酚；主要三卤甲烷生成活性排序为：间苯二酚〉4-氨基苯乙酮〉2-羟基-4-氨基甲苯〉对羟基苯甲酸。②卤乙酸的前期氯化反应速度排序为：间苯二酚〉4-氨基苯乙酮〉对羟基苯甲酸〉邻苯二酚；三卤甲烷的前期氯化反应速度排序为：对羟基苯甲酸〉2-羟基-4-氨基甲苯〉间苯二酚〉4-氨基苯乙酮．③对位或邻位取代基结构物质以生成卤乙酸为主；间位取代基结构物质以生成三卤甲烷为主．④苯环上羟基官能团生成消毒副产物的活性最高，酮基官能团次之；氨基官能团主要起到与其它活性官能团形成对位、邻位或间位结构的辅助作用；醛基和羧基官能团为惰性官能团；甲基官能团的作用有待深入考察。
英文摘要：
Some organic matter that have aromatic structure similar as humic acid are selected to conduct chlorination test, determined the formation of HAAs ＆ THMs of tested matters, researched the relationship of the chemical structure of DBPFP with DBPs formation characteristics. The results indicated that： ① The sequence of HAAs formation activity is p-Hydroxybenzoic acid 〉 p- Aminoacetophenone〉 o-Benzenediol 〉 m-Benzenediol; and THMs＇ s is m-Benzenediol 〉 p-Aminoacetophenone 〉 2-Hydroxy-p- aminoacetophenone〉 p-Hydroxybenzoic acid. ②The sequence of earlier chlorination reaction rate of HAAs is m-Benzenediol 〉 p- Aminoacetophenone〉 p-Hydroxybenzoic acid 〉 o-Benzenediol; and THMs＇ s is p-Hydroxybenzoic acid 〉 2-Hydroxy-p- aminoacetophenone〉 m-Benzenediol〉 p-Aminoacetophenone. ③The substances that having the substituent group structure of para ＆ ortho position are mostly format HAAs, and one＇s of having meta position are mostly format THMs. ④On the benzene ring, hydroxyl group has the highest activity of forming DBPs, and the second is ketone group; amino-group is play a part of auxiliary forming para, ortho or meta position structure mainly; aldehyde and carboxyl group are inert function group; the function of methyl group is remain to be determined.
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