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中文摘要：
以30％过氧化氢为氧化剂，考察了以杂多酸为催化剂氧化环己烯过程中离子液体的作用，讨论了离子液体种类和用量对反应的影响．结果表明，离子液体的加入顺序不同，其在催化过程中所起的作用不同．在反应条件为n（环己烯）：n（过氧化氢）：n（磷钨酸）：n（[（CH2）4SO3H-Py][HSO4]）=1：4．4：0．28：0．56，在回流温度下反应8h时，己二酸收率可达到84．9％。该催化剂体系可循环使用.
英文摘要：
Heteropoly acids （HPAs） are very attractive since their acidic and redox properties can be controlled at atomic or molecular levels. Among various HPAs structural classes, the Keggin-type HPAs containing tungstate and molybdenum have been widely employed not only for oxidation of organic substrates but also for many acid-catalyzed reactions due to their strong oxidizing ability and acid strength. Selective oxidation of lower hydrocarbons is of fundamental and technological interest because it provides a potential route to effectively transform lower hydrocarbon to higher, valueadded chemicals.
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