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中文摘要：
介绍了多金属氧酸盐的结构和性能,综述了这类化合物具有的多功能性和可调性,并对它们与环境温和、经济廉价的条件（溶剂,氧化剂等）的良好兼容性等特点进行了概述。多金属氧酸盐可以在原子/分子层次上进行催化剂的设计,在绿色催化和清洁生产等方面具有良好的应用前景。本文总结了多金属氧酸盐在液相清洁催化氧化方面的进展,主要针对以过氧化氢和分子氧为氧化剂的烯烃类化合物的环氧化反应、烷烃和芳香族化合物的氧化反应,并详细探讨了此类氧化反应的反应机理。同时也关注了多金属氧酸盐在仿生催化领域的应用。
英文摘要：
After a brief introduction to the structure and general properties of polyoxometalates, the unusual versatility and tunability and their compatibility with environmentally and economically attractive conditions （solvents, oxidants, etc. ） are outlined. These characteristics enable polyoxometalates suitable for catalyst to design at the atomic/ molecular levels and applicable in the aspects of green catalysis and clean production. Recent developments of clean oxidation systems catalyzed by polyoxometalates are summarized. The emphasis is on the epoxidation reaction of olefinic compounds, oxidation of alkanes and aromatic compounds with the comparatively ideal oxidants, hydrogen peroxide and molecular oxygen respectively. The oxidation mechanisms are elucidated in detail. In addition, the applications of polyoxometalates in the area of biomimetic catalysis are discussed.
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