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中文摘要：
均相催化由于具有反应条件温和、活性和选择性高等优点，在化学工业中被广泛地应用于催化合成有机化合物。本项目的研究目标是建立和发展定向合成含氧有机化合物的新型环境友好均相催化反应体系。1. 羰基化反应是催化合成有机化学品中最基本的含氧化合物的重要催化过程。重点开展具有催化功能的离子液体设计、合成与物理化学性质测定；以一氧化碳、二氧化碳、甲醛等为羰基化试剂，构建新型高效催化剂体系；新型手性配体及其金属配合物的设计、合成与结构表征，研究催化不对称羰基化反应的构效关系。2. 仿生催化氧化可在温和条件下实现分子氧选择性氧化烃类物质转变成含氧化合物。重点开展以过氧化氢和分子氧为氧源的烃类清洁催化氧化反应体系研究，探讨催化循环过程的作用机制和分子氧及底物的活化机理；建立高效的手性类卟啉金属催化剂催化不对称氧化反应体系。3. 生物催化是一类比较符合"绿色化学"的反应过程。重点开展具有高转化效能的甲烷利用菌菌株的选育，建立高效合成脂肪酸聚酯的甲烷生物催化转化体系；研究微水相或有机相中酶催化聚合、不对称拆分等反应，建立化学-生物顺序反应新方法。
结论摘要：
英文主题词environment friendly; homogeneous catalysis; carbonylation; selective oxidation; biocatalysis
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期刊论文
Enantioselective oxidation of secondary alcohols catalyzed by soluble chiral polymeric [N ',N '',bis
Magnetically separable Pd catalyst for carbonylative Sonogashira coupling reactions for the synthesi
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Synthesis of salan (salalen) ligands derived from binaphthol for titanium-catalyzed asymmetric epoxi
Synthesis and Structural Characterization of Silica Dispersed Copper Nanomaterials with Unusual Ther
Pyrrolidine-based Dicationic Acidic Ionic Liquids: Efficient and Recyclable Catalysts for Esterifica
Synthesis of Tridentate Ligands Based on Chiral Diamines and Their Application to Enantioselective F
Characterization and catalytic properties of the CuO/SiO2 catalysts prepared by precipitation-gel me
Synthesis, properties and catalysis of novel methyl- or ethyl-sulfate-anion-based acidic ionic liqui
Basic ionic liquids supported on hydroxyapatite-encapsulated gamma-Fe2O3 nanocrystallites: An effici
Synthesis of Novel Gemini Dicationic Acidic Ionic Liquids and Their Catalytic Performances in the Be
Novel acidic ionic liquids mediated zinc chloride: Highly effective catalysts for the Beckmann rearr
Lipase-catalysed kinetic resolution of secondary alcohols with improved enantioselectivity in propyl
Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffract
Highly dispersed silica-supported copper nanoparticles prepared by precipitation-gel method: A simpl
Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Rea
A simple and efficient recyclable phosphine-free catalytic system for alkoxycarbonylation and carbon
Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru-3(CO)(9){1
Zr(OTf)(4)-catalyzed direct three-component Mannich-type reaction of carbamates: An efficient one-st
Biosynthesis of poly-3-hydroxybutyrate with a high molecular weight by methanotroph from methane and
The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and
A magnetically recyclable heterogeneous catalyst: Cobalt nano-oxide supported on hydroxyapatite-enca
A Pd(OAc)(2)/[mmim]I catalyst system for oxidative carbonylation of amines to carbamates, ureas, and
p-Toluenesulfonic acid mediated zinc chloride: Highly effective catalyst for the Beckmann rearrangem
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