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钨酸钠与酸性离子液体催化醇的环境友好氧化反应
  • ISSN号：1001-3555
  • 期刊名称：《分子催化》
  • 时间：0
  • 分类：O643.32[理学—物理化学;理学—化学]
  • 作者机构：[1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000, [2]中国科学院研究生院,北京100049
  • 相关基金：Foundation item： Funded by NSFC （No. 20373082 and No. 20625308）.
作者： 郎贤军[1,2], 李臻[1], 夏春谷[1]
关键词： 醇的氧化, 钨酸钠, 离子液体, 双氧水, Alcohol oxidation , Sodium tungstate , Ionic liquid , Hydrogen peroxide
中文摘要：

钨酸钠与酸性离子液体组成的催化体系可以催化双氧水进行醇的清洁氧化，反应在有机底物／水两相中进行．本体系在催化氧化仲醇为相应的酮时具有很好的活性；催化伯醇氧化时可以得到相应的醛、羧酸或两者的混合物．整个催化体系具有很好的重复利用性．

英文摘要：

Oxidation of alcohols to the corresponding carbonyl compounds is one of the fundamental functional group transformations in organic synthesis .Generally, these reactions require stoichiometric amounts of inorganic/organic oxidants, toxic or hazardous oxidizing agents. Environmentally benign and sustainable transformations in organic chemistry are now considered to be basic goals and requirements in the development of modern organic syntheses.

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期刊信息
  • 《分子催化》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院兰州化学物理研究所
  • 主编：李树本
  • 地址：兰州市天水路18号
  • 邮编：730000
  • 邮箱：fzch@licp.cas.cn
  • 电话：0931-4968226
  • 国际标准刊号：ISSN：1001-3555
  • 国内统一刊号：ISSN：62-1039/O6
  • 邮发代号:54-69
  • 获奖情况:
  • 1992年获中国科学院优秀期刊三等奖,1992年获甘肃省第二届优秀科技期刊荣誉称号
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:7932