位置：成果数据库 > 期刊 > 期刊详情页
末端炔烃二聚反应合成共轭烯炔的研究进展
  • 期刊名称：有机化学，2007，27，1078-1086
  • 时间：0
  • 分类：O623.124[理学—有机化学;理学—化学]
  • 作者机构：[1]湖南师范大学化学化工学院化学生物学与中药分析教育部重点实验室,长沙410081, [2]湘南学院化学与生命科学系,郴州423000
  • 相关基金：湖南省教育厅基金（No.05B038）、国家自然科学基金（No.20572020）、霍英东教育基金会第十届高等院校青年教师基金（No.101012）、湖南省杰出青年基金（No.05JJ1002）和教育部重点项目基金（No.206102）资助项目.
  • 相关项目：胺作为配体在钯催化偶联反应中应用研究
关键词： 末端炔烃, 二聚反应, 烯炔化合物, 选择性, terminal alkyne, dimerization reaction, enyne, selectivit
中文摘要：

综述了不同催化体系催化末端炔烃二聚反应合成共轭烯炔化合物的研究进展．其中催化体系主要包括过渡金属配合物、镧系和锕系金属配合物、第三主族元素配合物以及有机催化剂．实验结果表明：不同催化体系对末端炔烃二聚反应的选择性控制有影响，尤其是区域选择性（头-头二聚或头-尾二聚）．

英文摘要：

Progress in a variety of catalytic systems-catalyzed dimerizations of terminal alkynes to synthesize enynes is summarized. These catalytic systems included transition-metal complexes, organolanthanide and organoactinium complexes, IliA element complexes and organic catalysts. The results showed that the catalytic systems had a fundamental influence on the selectivity, in particular regioselectivity （head-to- head or head-to-tail）, of the dimerization reactions of terminal alkynes.

同期刊论文项目
胺作为配体在钯催化偶联反应中应用研究
期刊论文 46 会议论文 3
同项目期刊论文
2-Aminopyrimidine-4,6-diol as an Efficient Ligand for Solvent-Free Copper-Catalyzed N-Arylations of
Improved Procedure for Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Aryl Halides with Arylt
Cu(OAc)2/DAB-Ph-Catalyzed Sonogashira Cross-Couplings of Aryl Halides with Terminal Alkynes under Ae
Polymer-Supported DABCO-Palladium Complex as A Stable and Reusable Catalyst for Room Temperature Suz
CuI/DABCO-catalyzed cross-coupling reactions of aryl halides with arylboronic acids
Selective (-Bromination of (-Keto Esters in Reusable PEG-400 under Mild and Catalyst-Free Conditions
硫酸高铈催化炔烃的水合反应研究
胺作为配体在钯催化交叉偶联反应中应用
Copper/Silver-Cocatalyzed Conia-Ene Reaction of Linear (-Alkynic (-Ketoesters
Novel and Selective Palladium-Catalyzed Annulations of 2-Alkynylphenols To Form 2-Substituted 3-Halo
General and Modified Palladium-Catalyzed Sonogashira Cross-Coupling Reaction under Copper-, Amine- a
Cu(OAc)2/Pyrimidines-Catalyzed Cross-Coupling Reactions of Aryl Iodides and Activated Aryl Bromides
Solvent-free copper/iron co-catalyzed N-arylation reactions of nitrogen-containing heterocycles with
Solvent-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Chlorides with Arylboronic A
不饱和烃Heteropalladation反应在有机合成中的应用
Sequential Intermolecular Aminopalladation/ortho-Arene C-H Activation Reactions of N-Phenylpropiolam
Cycloaddition of Arynes with Iodonium Ylides: A Mild and General Route for the Synthesis of Benzofur
Palladium-Catalyzed Carbonylative Annulation Reaction of 2-(1-Alkynyl)benzenamines: Selective Synthe
Synthesis of (2-Oxoindolin-3-ylidene)methyl Acetates Involving a C?H Functionalization Process
PdX2/CuX2-Catalyzed Annulation of 2-Ethynylbenzenamines: Selective Synthesis of 3-Halo-2-substituted
N-Arylations of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides Using Cu2O Nanopar
Electrophilic ipso-Iodocyclization of N-(4-Methylphenyl)propiolamides: Selective Synthesis of 8-Meth
Cu(OAc)2-Catalyzed Sonogashira Cross-coupling Reaction in Amines
CuI-Catalyzed Suzuki-Miyaura and Sonogashira Cross-Coupling Reactions Using DABCO as Ligand
Reusable Cu2O/PPh3/TBAB System for the Cross-Couplings of Aryl Halides and Heteroaryl Halides with T
TBAB-Promoted Ligand-Free Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Arylboronic
Halogenations of Indoles with CuX2: Selective Synthesis of 2-Halo-, 3-Halo- and 2,3-Dibromoindoles
(-Keto Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Co
Mild and ligand-free palladium-catalyzed cross-couplings of aryl halides with arylboronic acids to s
Palladium-Catalyzed C-H Functionalization of N-Arylpropiolamides with Aryliodonium Salts: Selective
Electrophilic ipso-Cyclization of N-(p-Methoxyaryl)propiolamides Involving An Electrophile-Exchange
Palladium-Catalyzed Cross-Coupling Reactions of 1,2-Diiodoalkenes with Terminal Alkynes: Selectively
Reusable and Ligand-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Halides with Ary
Halopalladation/Decarbonylation/Carbon-Carbon Forming Domino Process: Synthesis of 5-Halo-6-substitu
Copper/Silver-Cocatalyzed Conia-Ene Reactions of 2-Alkynic 1,3-Dicabonyl Compounds,
Electrophilic ipso-Halocyclization of N-Arylpropiolamides with Polyfluoroalkyl Alcohols: Selective S
Generation of Pd Nanoparticles in situ from PdCl2 in TBAF: an Efficient and Reusable Catalytic Syste
Selective Synthesis of Spiro[4,5]trienyl Acetates via An Intramolecular Electrophilic ipso-Iodocycli
Cy2NH(HX-Promoted Cyclizations of o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoate with Copper Halide
Reusable Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Organotins in Inexpensive Io
Pd(OAc)2/DABCO-catalyzed Suzuki-Miyaura cross-coupling reaction in DMF
不饱和烃杂钯化反应在有机合成中的应用
胺作为配体在钯催化偶联反应中应用
Selective α-Bromination of β-Keto Esters in Reusable PEG-400 under Mild and Catalyst-free Conditions
Cu（OAc）2/Pyrimidines-Catalyzed Cross-coupling Reactions of Aryl Iodides and Activated Aryl Bromides with Alkynes under Aerobic, Solvent-free and Palladium-free Conditions