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中文摘要：
不饱和烃杂钯化反应是合成高活性反应中间体烷基钯（Ⅱ）和烯丙基钯（Ⅱ）重要的途径.这些钯的络合物,在合适的条件下能被各种亲核试剂例如烯丙基卤、一氧化碳、不饱和烃、有机硼、有机锡等捕获.经过一系列插入及消除反应,能够有效地构建多种生理活性药物、有机功能分子以及重要合成骨架.近年来,引起了有机合成工作者的兴趣.在这里,对杂钯化最新进展进行综述.
英文摘要：
The heteropalladation reactions of unsaturated hydrocarbons are some of the most important routes to generate highly active alkylpalladium（Ⅱ） and vinylpalladium（Ⅱ） species. Under appropriate conditions, they can be trapped by some nucleophiles such as allylhalogens, carbon monoxide, unsaturated hydrocarbons, organoboric reagents and organostannic reagents etc. Followed by insertion and/or elimination to produce a variety of bioactive medicines, functional molecules and important building blocks. Recently, much attention has been attracted in the heteropalladation reactions. Here, recent advances in the heteropalladation reactions are reviewed.
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Improved Procedure for Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Aryl Halides with Arylt
Cu(OAc)2/DAB-Ph-Catalyzed Sonogashira Cross-Couplings of Aryl Halides with Terminal Alkynes under Ae
Polymer-Supported DABCO-Palladium Complex as A Stable and Reusable Catalyst for Room Temperature Suz
Selective (-Bromination of (-Keto Esters in Reusable PEG-400 under Mild and Catalyst-Free Conditions
Novel and Selective Palladium-Catalyzed Annulations of 2-Alkynylphenols To Form 2-Substituted 3-Halo
General and Modified Palladium-Catalyzed Sonogashira Cross-Coupling Reaction under Copper-, Amine- a
Solvent-free copper/iron co-catalyzed N-arylation reactions of nitrogen-containing heterocycles with
Solvent-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Chlorides with Arylboronic A
Sequential Intermolecular Aminopalladation/ortho-Arene C-H Activation Reactions of N-Phenylpropiolam
Cycloaddition of Arynes with Iodonium Ylides: A Mild and General Route for the Synthesis of Benzofur
Palladium-Catalyzed Carbonylative Annulation Reaction of 2-(1-Alkynyl)benzenamines: Selective Synthe
PdX2/CuX2-Catalyzed Annulation of 2-Ethynylbenzenamines: Selective Synthesis of 3-Halo-2-substituted
N-Arylations of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides Using Cu2O Nanopar
Electrophilic ipso-Iodocyclization of N-(4-Methylphenyl)propiolamides: Selective Synthesis of 8-Meth
Reusable Cu2O/PPh3/TBAB System for the Cross-Couplings of Aryl Halides and Heteroaryl Halides with T
TBAB-Promoted Ligand-Free Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Arylboronic
(-Keto Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Co
Mild and ligand-free palladium-catalyzed cross-couplings of aryl halides with arylboronic acids to s
Palladium-Catalyzed Cross-Coupling Reactions of 1,2-Diiodoalkenes with Terminal Alkynes: Selectively
Reusable and Ligand-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Halides with Ary
Halopalladation/Decarbonylation/Carbon-Carbon Forming Domino Process: Synthesis of 5-Halo-6-substitu
Electrophilic ipso-Halocyclization of N-Arylpropiolamides with Polyfluoroalkyl Alcohols: Selective S
Generation of Pd Nanoparticles in situ from PdCl2 in TBAF: an Efficient and Reusable Catalytic Syste
Selective Synthesis of Spiro[4,5]trienyl Acetates via An Intramolecular Electrophilic ipso-Iodocycli
Cy2NH(HX-Promoted Cyclizations of o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoate with Copper Halide
Reusable Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Organotins in Inexpensive Io
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