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中文摘要：
本申请拟进行研究的内容（1）通过设计、合成和筛选出在偶联反应中具有高活性的胺配体及钯-胺配合物催化剂；（2）通过使用PEG、水和二氧化碳为介质，以及分别对钯催化剂和胺配体固载化，改善或实现反应绿色化。通过该项研究，发现并揭示在胺配体作用下钯催化偶联反应所表现出的新现象和规律,发展具有高效、高选择性和绿色的钯催化偶联反应新方法和技术，并将该方法和技术应用到合成某些具有生理活性的天然产物及药物中去。这项研究将不断丰富有机化学的内涵，为拓宽胺和钯催化偶联反应的应用提供新途径，从而进一步促进和实现资源高值化及绿色化利用。
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期刊论文
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期刊论文
Improved Procedure for Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Aryl Halides with Arylt
Cu(OAc)2/DAB-Ph-Catalyzed Sonogashira Cross-Couplings of Aryl Halides with Terminal Alkynes under Ae
Polymer-Supported DABCO-Palladium Complex as A Stable and Reusable Catalyst for Room Temperature Suz
Selective (-Bromination of (-Keto Esters in Reusable PEG-400 under Mild and Catalyst-Free Conditions
Novel and Selective Palladium-Catalyzed Annulations of 2-Alkynylphenols To Form 2-Substituted 3-Halo
General and Modified Palladium-Catalyzed Sonogashira Cross-Coupling Reaction under Copper-, Amine- a
Solvent-free copper/iron co-catalyzed N-arylation reactions of nitrogen-containing heterocycles with
Solvent-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Chlorides with Arylboronic A
Sequential Intermolecular Aminopalladation/ortho-Arene C-H Activation Reactions of N-Phenylpropiolam
Cycloaddition of Arynes with Iodonium Ylides: A Mild and General Route for the Synthesis of Benzofur
Palladium-Catalyzed Carbonylative Annulation Reaction of 2-(1-Alkynyl)benzenamines: Selective Synthe
PdX2/CuX2-Catalyzed Annulation of 2-Ethynylbenzenamines: Selective Synthesis of 3-Halo-2-substituted
N-Arylations of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides Using Cu2O Nanopar
Electrophilic ipso-Iodocyclization of N-(4-Methylphenyl)propiolamides: Selective Synthesis of 8-Meth
Reusable Cu2O/PPh3/TBAB System for the Cross-Couplings of Aryl Halides and Heteroaryl Halides with T
TBAB-Promoted Ligand-Free Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Arylboronic
(-Keto Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Co
Mild and ligand-free palladium-catalyzed cross-couplings of aryl halides with arylboronic acids to s
Palladium-Catalyzed Cross-Coupling Reactions of 1,2-Diiodoalkenes with Terminal Alkynes: Selectively
Reusable and Ligand-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Halides with Ary
Halopalladation/Decarbonylation/Carbon-Carbon Forming Domino Process: Synthesis of 5-Halo-6-substitu
Electrophilic ipso-Halocyclization of N-Arylpropiolamides with Polyfluoroalkyl Alcohols: Selective S
Generation of Pd Nanoparticles in situ from PdCl2 in TBAF: an Efficient and Reusable Catalytic Syste
Selective Synthesis of Spiro[4,5]trienyl Acetates via An Intramolecular Electrophilic ipso-Iodocycli
Cy2NH(HX-Promoted Cyclizations of o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoate with Copper Halide
Reusable Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Organotins in Inexpensive Io
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