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中文摘要：
对近期我们研究小组及其它研究小组在利用胺作为钯催化偶联反应的配体研究进展进行了总结．钯／胺作为催化体系主要应用的偶联反应包括：Suzuki—Miyaura交叉反应，Sonogashira交叉反应，Stille交叉反应，Hiyama交叉反应和Heck反应．研究结果表明胺可以作为价廉和高效的配体促进钯催化交叉偶联反应．
英文摘要：
Progress of our group and the other groups＇ recent work in the field of palladium-catalyzed coupling reactions using amine as the ancillary ligands is summarized. The coupling reactions using the combination of palladium and amines as the catalytic system include the Suzuki-Miyaura cross-coupling reaction, Sonogashira cross-coupling reaction, Stille cross-coupling reaction, Hiyama cross-coupling reaction and Heck reaction. The results show that amine could be used as the inexpensive and highly efficient ligands to promote the palladium-catalyzed coupling reactions.
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Selective α-Bromination of β-Keto Esters in Reusable PEG-400 under Mild and Catalyst-free Conditions
Improved Procedure for Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Aryl Halides with Arylt
Cu(OAc)2/DAB-Ph-Catalyzed Sonogashira Cross-Couplings of Aryl Halides with Terminal Alkynes under Ae
Polymer-Supported DABCO-Palladium Complex as A Stable and Reusable Catalyst for Room Temperature Suz
Selective (-Bromination of (-Keto Esters in Reusable PEG-400 under Mild and Catalyst-Free Conditions
Novel and Selective Palladium-Catalyzed Annulations of 2-Alkynylphenols To Form 2-Substituted 3-Halo
General and Modified Palladium-Catalyzed Sonogashira Cross-Coupling Reaction under Copper-, Amine- a
Solvent-free copper/iron co-catalyzed N-arylation reactions of nitrogen-containing heterocycles with
Solvent-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Chlorides with Arylboronic A
Sequential Intermolecular Aminopalladation/ortho-Arene C-H Activation Reactions of N-Phenylpropiolam
Cycloaddition of Arynes with Iodonium Ylides: A Mild and General Route for the Synthesis of Benzofur
Palladium-Catalyzed Carbonylative Annulation Reaction of 2-(1-Alkynyl)benzenamines: Selective Synthe
PdX2/CuX2-Catalyzed Annulation of 2-Ethynylbenzenamines: Selective Synthesis of 3-Halo-2-substituted
N-Arylations of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides Using Cu2O Nanopar
Electrophilic ipso-Iodocyclization of N-(4-Methylphenyl)propiolamides: Selective Synthesis of 8-Meth
Reusable Cu2O/PPh3/TBAB System for the Cross-Couplings of Aryl Halides and Heteroaryl Halides with T
TBAB-Promoted Ligand-Free Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Arylboronic
(-Keto Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Co
Mild and ligand-free palladium-catalyzed cross-couplings of aryl halides with arylboronic acids to s
Palladium-Catalyzed Cross-Coupling Reactions of 1,2-Diiodoalkenes with Terminal Alkynes: Selectively
Reusable and Ligand-Free Palladium-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Halides with Ary
Halopalladation/Decarbonylation/Carbon-Carbon Forming Domino Process: Synthesis of 5-Halo-6-substitu
Electrophilic ipso-Halocyclization of N-Arylpropiolamides with Polyfluoroalkyl Alcohols: Selective S
Generation of Pd Nanoparticles in situ from PdCl2 in TBAF: an Efficient and Reusable Catalytic Syste
Selective Synthesis of Spiro[4,5]trienyl Acetates via An Intramolecular Electrophilic ipso-Iodocycli
Cy2NH(HX-Promoted Cyclizations of o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoate with Copper Halide
Reusable Copper-Catalyzed Cross-Coupling Reactions of Aryl Halides with Organotins in Inexpensive Io
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