以SF6和SF6+Ar为刻蚀气体。采用电子回旋共振等离子体刻蚀工艺成功地对溶胶.凝胶工艺制备的锆钛酸铅铁电薄膜进行了有效的刻蚀去除.研究了不同气体总漉量、混合比、微波功率等因素对刻蚀速率的影响。指出当气体混合比约为20%时。刻蚀速率达到最大值.锆钛酸铅铁电薄膜表面组份XPS能谱分析曲线表明,在SF6和SF6+Ar气体中。被刻蚀后样品的Pb含量大大减少。TiO2的刻蚀是限制铬钛酸铅铁电薄膜刻蚀速率的主要因素.
Electron cyclotron resonance (ECR) etching of the lead zirconate titanate (PZT) ferroelectric thin films produced via sol-gel process has been performed in SF6 and the SF6 + Ar mixtures. The dependence of the etching rate on the total flow rate, gas mixing ratio and microwave power density has been systematically investigated. Experimental results show that the maxima of the etching rate is reached when the gas mixing ratio is about 20%. The surface component X-ray photoelectron spectroscopy (XPS) of PZT thin films indicate that the ECR etching process in SF6 and the SF6 + Ar mxtures yield a great decrease in Pb content in the composition of PZT thin films, and that the etching of TiO2 is the major factor in restricting the PZT thin films etching rate.