采用极化曲线,塔菲尔图(Tafel Plot),交流阻抗(EIS)及浸泡腐蚀技术,研究了激光熔化沉积γ/Mo2Ni3Si合金在不同酸,碱,盐介质中的腐蚀行为。结果表明,该合金在1mol/L NaOH溶液中,由于形成了稳定的钝化膜,耐蚀性优异;在1mol/LH2SO4溶液中,合金只能形成不稳定的钝化膜;而在含Cl^-的中性或酸性介质中,合金没有钝化趋势,且由浸泡腐蚀试验表明,在1mol/LHCl溶液中,由于Cl^-导致相界腐蚀,合金耐蚀性较差。
The corrosion behavior of Laser melting-deposited γ/Mo2Ni3Si alloy consisting of Mo2Ni3Si primary dendrites and Mo2Ni3Si/γ eutectic matrix in different mediums were investigated by polarization curve, Tafel Plot, EIS and immersion corrosion. Results showed that the alloy has excellent corrosion resistance in NaOH solution of 1 mol/L owing to the formation of stable passivation film. Unstable passivation film was formed in H2SO4 solution of 1 mol/L. No passivation occurred in neutral or acid solutions containing Cl^- The alloy exhibited very poor corrosion resistance during the immersion test in HCI solution of 1 mol/L due to the preverential phase-boundary corrosion by Cl^-.