中文摘要：

为改善催化剂的溶解性能，以寻求更高效的光催化剂，以1，3-二亚氨基异吲哚啉和2，3-二氰基-1，4-二噻英为原料，用固相法合成了不对称型1，4-二噻英-二苯基四氮杂卟啉铁FePcPz（dtn）。及其氯代改性FePcClPz（dtn）4．对所得产物进行了UV—Vis、IR、X-射线光电子能谱（XPS）表征．考察了产物的溶解性能，利用高效液相色谱法对产物进行了分离研究．

英文摘要：

To improve the solubility properties and find highly efficient photocatalysis materials, the assymmetric iron （ Ⅱ ） 1,4-dithiin-diphenyl porphyrazine FePcPz（dtn）4 and its chloridized ,FePcC1Pz（dtn）4 were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method. The products were analyzed by HPLC and their structures were characterized by UV＇-vis, FT-IR and X-ray photoemission spectroscopies and their solubility properties were investigated roughly.