中文摘要：

为寻求更高效的光催化剂，以1，3-二亚氨基异吲哚啉和2，3-二氰基-1，4-二噻英为原料，钼酸铵为催化剂，七水合硫酸亚铁为模板，用固相法合成了二（1，4-二噻英）-二苯基四氮杂卟啉铁（FePzPh（dtn）4），并对其进行了磺化改性（FePzSPh（dtn）4）．2种产物的结构经过UV-Vis、IR、^1H—NMR、X-射线光电子能谱（XPS）表征，并初步探讨了其溶解性能．

英文摘要：

To find highly efficient photocatalysis materials, complex iron （ Ⅱ ） 1,4-dithiin-diphenyl porphyrazine （FePzPh（dtn）4） and its sulfonation derivatives （FePzSPh（dtn）4） were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method using ammonium molybdate as a catalyst in the presence of ferrous sulfate heptahydrate. Their structures were characterized by UV-vis, FT-IR,^1H-NMR and X-ray photoemission spectra and their solubility properties were investigated roughly.