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中文摘要：
将以L-脯氨酸为原料合成的光学活性脯氨醇衍生物（（S）-2-吡咯烷基-α，α-（α萘基）甲醇1），作为有机小分子催化剂，在催化8种α，β-不饱和酮的不对称环氧化反应中表现出较好的立体选择性（58．0～84．6％ee）和催化活性（58．0～89．7％）．反应结束后，通过简单的酸碱调整，可使催化剂回收和重复使用．循环使用5次，催化剂的回收率均在93～97％之间，催化剂的催化活性和立体选择性无明显改变．
英文摘要：
Starting from （S） -proline, a new （S） -prolinol derivative, （S） -2-（ di-α- naphthylhydroxyl methyl） pyrrolidine 1, was prepared and applied in the organocatalytic asymmetric epoxidation of eight α,β-enones. The organocatalyst displayed high enantioselectivities （58.0% - 84.6% ） and catalytic reactivities （58.0% - 89.7% yields）. The catalyst was recovered almost by a simple acid-base adjustment and reused for five cycles without obvious decreased enantioselectivities and catalytic reactivities, with 93% - 97% recovery of catalyst.
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