把BiGaO3作为第三组元引入BiScO3-PbTiO3(BS—PT)体系,用氧化物合成法制备、了0.155BiGaO3-(0.845-x)BiScO3-xPbTiO3(BGSPTx,x为0.54-0.58)压电陶瓷。XRD分析表明,BGSPL具有钙钛矿结构,但同时存在微量的富铋相。三方-四方准同型相界(MPB)位于x为0.56附近。在MPB附近,BGSPTx陶瓷的d33,kp和Pr都达到最大值,分别为180pC/N,30%和18.5×10^-6C/cm^2。εr-t特性曲线测试表明,陶瓷在MPB附近居里温度抽高达494℃。
BiGaO3 was introduced into the BiScO3-PbTiO3 (BS-PT) system and formed a new type of ceramics 0.155BiGaO3-(0.845-x)BiScO3-xPbTiO3 (BGSPTx, x = 0.54-0.58). BGSPTx ceramics were fabricated by using conventional mixed metal oxide processing. X-ray diffraction shows that the BGSPTx ceramics have perovskite structure, however, a small amount of the plenty Bi phase is detected. A rhombohedral to tetragonal phase transition (MPB) is determined in the vicinity of x = 0.56. For composition near MPB, BGSPTx ceramics show enhanced piezoelectric coefficient d33, planar coupling coefficient kp and remnant polarization Pr of 180 pC/N, 30%, and 18.5×10^-6 C/cm^2, respectively. The ,εr-t dependence of BGSPTx ceramics are performed, and its tc is 494 ℃ around MPB.