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载铜ZSM-5分子筛膜脱除硫醇性能
  • 期刊名称:化工进展, 2008,27(11):1825-1828.
  • 时间:0
  • 分类:TQ028.8[化学工程]
  • 作者机构:[1]南京工业大学材料化学工程国家重点实验室,江苏南京210009
  • 相关基金:国家自然科学基金(20436030)及江苏省重点实验室开放课题(KJS03017)资助项目.
  • 相关项目:新型分离材料的制备与应用的关键科学问题
中文摘要:

采用一次水热合成法,制得ZSM-5分子筛膜,用XRD和扫描电镜对膜的物理及化学结构进行了分析表征。所制得的膜用于正己烷中硫醇的脱除,研究了不同膜通量、负载离子浓度和料液温度对膜性能的影响。结果表明:渗透通量大,对硫醇的脱除不利;铜离子的引入大大提高了分子筛膜管的截留性能,但负载铜离子过高会降低模拟汽油的通量;操作温度升高,渗透通量增加,膜对硫醇的脱除率下降。

英文摘要:

Membranes of ZSM-5 zeolite were obtained by one step in situ hydrothermal synthesis. XRD and SEM micrographs were used to characterize these membranes. The membranes were used for the separation of ethanethiol from n-hexane. It was shown from the result that: the desulfurizing effect decreased with increasing permeation rate; and the rejection performance was enhanced after the membranes were loaded with Cu^2+. However, high concentration of Cu^2+ decreased the permeation rate. It was also found that at a higher operation temperature, the permeation rate increased while the desulfurizing effect decreased.

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