位置：成果数据库 > 期刊 > 期刊详情页
A molecular half-adder and half-subtractor based on pyrylium
  • ISSN号：1001-6538
  • 期刊名称：Chinese Science Bulletin
  • 时间：0
  • 页码：2799-2802
  • 分类：O561.1[理学—原子与分子物理;理学—物理] TP342.21[自动化与计算机技术—计算机系统结构;自动化与计算机技术—计算机科学与技术]
  • 作者机构：[1]Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
  • 相关基金：This paper is dedicated to Professor LIU YouCheng on the occasion of his 90th birthday. This work was supported by the National Basic Research Program of China （2004CB719905）, the National Natural Science Foun- dation of China （20832004, 20472038, 20721062 and 20672060） and the 111 Project （B06005）.
  • 相关项目：有机负氢化合物中的物理有机化学问题
作者： Cao ChaoTun|Liu Hui|Zhu Xiao-Qing|Cheng Jin-Pei|
关键词： 分子离子, 半加器, 减法, 吡喃, 基础, 逻辑系统, 氨基苯基, 功能变化, molecular devices, half-subtractor, half-adder, 4-（4-dimethylaminophenyl）-2,6-diphenylpyrylium
中文摘要：

一个很简单的分子的阳离子， 4-(4-dimethylaminophenyl )-2,6-diphenylpyrylium, 被表明了响应酸和底的输入根据分子的系统的可检测的分光镜的变化有分子的一半蝮蛇和一半消减器的功能。不同代数学的手术能在这个可配置的分子的逻辑系统被动。

英文摘要：

A very simple molecular cation, 4-（4-dimethylaminophenyl）-2,6-diphenylpyrylium, has been demonstrated to have a function of molecular half-adder and half-subtractor according to the detectable spectroscopic changes of the molecular system in response to the inputs of acid and base. Distinct algebraic operations can be performed in this reconfigurable molecular logic system.

同期刊论文项目
负载单电子转移诱导基团的烟酰胺辅酶新型模型物设计、合成及应用
期刊论文 16
有机和生物有机不饱和化合物负氢亲合势的测定
期刊论文 11
功能有机分子的构筑和构效关系研究
期刊论文 199
有机负氢化合物中的物理有机化学问题
期刊论文 29
同项目期刊论文
A soluble polymer-supported NADH model: Synthesis and application
Hydride Affinities of Cumulated, Isolated, and Conjugated Dienes in Acetonitrile
Driving forces for the mutual conversions between phenothiazines and their various reaction intermed
Establishment of heterolytic and homolytic Y-NO2 bond dissociation energy scales of nitro-containing
Hydride, hydrogen atom, proton, and electron transfer driving forces of various five-membered hetero
Theoretical prediction of the hydride affinities of various p- and o-quinones in DMSO
Mechanism and driving force of NO transfer from S-nitrosothiol to cobalt(II) porphyrin: A detailed t
一种基于吡喃鎓离子的分子半加器和半减器研究
可溶性聚乙二醇负载的烟酰胺辅酶模型物设计合成及应用
Mechanism 6of NO Transfer from
A soluble polymer-supported NADH model: Synthesis and application
Hydride, Hydrogen Atom, Proton
乙腈溶液中亚硝酸苄（醇）酯系列化合物NO化学亲和势的测定
S-亚硝基-N-乙酰基-D，L-青霉胺二肽分子中S—NO键断裂能的测定
1,4-与1,2-二氢NADH模型物反应活性的比较
烟酰胺辅酶反应中心结构选择1，4-二氢烟酰胺的热力学和动力学根源
一种基于吡喃鎓离子的分子半加器和半减器研究
Scales of Oxidation Potentials, pK(a), and BDE of Various Hydroquinones and Catechols in DMSO
Kinetics and Mechanism Studies of the Decay of Retinol and Retinyl Acetate in Micellar Solutions
Hydride, Hydrogen, Proton, and Electron Affinities of Imines and Their Reaction Intermediates in Ace
Hydride Affinity Scale of Various Substituted Arylcarbeniums in Acetonitrile
A soluble polymer-supported NADH model: Synthesis and application
Thermodynamic Diagnosis of the Properties and Mechanism of Dihydropyridine-Type Compounds as Hydride
Accurate Estimation of the One-Electron Reduction Potentials of Various Substituted Quinones in DMSO
Kinetics of Hydride Abstractions from 2-Arylbenzimidazolines
Establishment of the C-NO Bond Dissociation Energy Scale in Solution and Its Application in Analyzin
Comparison of the reactivity between 1,4 and 1,2-dihydro NADH models
Thermodynamics and kinetics superiorities of 1,4-dihydronicotinamide as the activation center of NAD
New redox anion receptors based on calix[4]pyrrole bearing ferrocene amide
一种基于吡喃鎓离子的分子半加器和半减器研究
可溶性聚乙二醇负载的烟酰胺辅酶模型物设计合成及应用
铬族金属氢化物中M—H键键能的从头计算
有机自由基基团的哈米特σp常数的理论研究
Theoretical estimation of Hammett σpconstants of organic radical groups
A soluble polymer-supported NADH model: Synthesis and application
A modified total synthesis of cystothiazole A
Synthesis and Characterization of the Monomeric Vicinal Dianion and the Aluminum and Lithium Derivat
Synthesis and Reactivity of Nickel Complexes with Sulfonamido-Imine Ligand
A capillary electrophoresis assay for protoporphyrinogen oxidase
Catalytic enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by a
Quadruple Hydrogen Bonded Self-assemblies of 5,5’-bisdiazo-dipyrromethane
Friedel-Crafts Alkylation of Arenes with Epoxides Promoted by Fluorinated Alcohols
Synthesis, structures and norbornene polymerization behavior of bis(aryloxide-N-heterocyclic carbene
A n-BuLi-Mediated Expeditious and Stereoselective Ring-Opening Rearrangement of Aryl Methylenecyclop
Effect of lower-rim alkylation of p-sulfonatocalix[4]arene on the thermodynamics of host–guest compl
Molecular binding behaviours of bile salts by bridged and metallobridged bis(β-cyclodextrin)s with n
Highly Diastereoselective Gold- or Copper-Catalyzed Formal [4+3] Cycloaddition of 1-(1-Alkynyl) Cycl
Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols
Reactions of the doubly bridged bis(cyclopentadienyl) dinuclear molybdenum complex (Me2C)(Me2Si)[((5
Design and synthesis of N-2,6-difluorophenyl-5-methoxyl- 1,2,4-triazolo[1,5-a]- pyrimidine- 2-sulfo
Artemether/hydroxypropyl-(-cyclodextrin host–guest system: characterization, phase-solubility and in
Inclusion complexes of bisphenol A with cyclomaltoheptaose ((-cyclodextrin): solubilization and stru
Synthesis of l-cystine modified cyclodextrin monomers and dimers with primary-side versus secondary-
Syntheses of dibenzo-18-crown-6 lariat isomers and their complexation with lanthanoid nitrates
Critical stereocontrol by inter-amino distance of supramolecular photocyclodimerization of 2-anthrac
Thermodynamics of complexes between nucleobase-modified (-cyclodextrins and bile salts
Novel Hydrophilic Cages Based on Acetone Complex with Calix[4]arene Dimethoxycarboxylic Acid
Construction, DNA wrapping and cleavage of a carbon nanotube–polypseudorotaxane conjugatew
A polymeric pseudorotaxane constructed from cucurbituril and aniline, and stabilization of its radic
A highly regioselective tandem 1,3-dipolar cycloaddition of cyclopropene 1,1-diesters and nitrile ox
Syntheses and Self-Assembly Behaviors of the Azobenzenyl Modified (-Cyclodextrins Isomers
Colorimetric Sensor and Inverse Fluorescent Behavior of Anions by Calix[4]arene Possessing Imidazo[4
Enantioselective synthesis of chiral (-aryloxyalcohols by ruthenium-catalyzed ketone hydrogenation v
Benzenesulfonamidoquinolino-β-cyclodextrin as a cell-impermeable fluorescent sensor for Zn2+
Highly enantioselective hydrogenation of (-arylmethylene cycloalkanones catalyzed by iridium complex
Desymmetrization of meso-1,2-Diols via the Dynamic Kinetic Resolution of Its Monodichloroacetates
Application of TFA and BF3·ET2O in the Synthesis of Dithiaporphyrins
The Synthesis of A Novel Bisimidazolium Branched Zinc Metallporphyrin and Its Recognition for Halide
One-dimensional inclusion polymers of calix[4]arene monomethoxycarboxylic acid
Synthesis, structure, and ring-opening metathesis polymerization of (5-pentamethylcyclopentadienyl-
喹啉修饰β-环糊精键合胆酸客体的热力学研究
均苯三酰胺桥联三环糊精/Zn2+/金刚烷衍生物三元超分子体系的合成及其羧肽酶A模拟研究
钾离子调控的1,5-萘基桥联双冠醚的"off-on-off"和"on-off-on"行为
S-亚硝基-N-乙酰基-D,L-青霉胺二肽分子中S-NO键断裂能的测定
双吲哚基修饰杯[4]芳烃对Hg2+的比色传感行为
Supramolecular architectures by fullerene-bridged bis(permethyl-(-cyclodextrin) s with porphyrins
N-Heterocyclic Carbene-Catalyzed Domino Ring-Opening/Redox Amidation/Cyclization Reactions of Formyl
ntramolecular Si?Si Bond Activation by the Iron Carbonyl Unit in an (η4-Silole)tricarbonyliron Compl
Synthesis and Properties of Structural Variants of the Si–Si Bridged Bis(cylcopentadienyl)tetracarbo
Synthesis, structures and polymerization catalytic properties of doubly bridged biscyclopentadienyl
Azaphosphaallyl anion lithium and its monomeric potassium and thallium complexes
A Simple yet Highly Selective Colorimetric Sensor for Cyanide Anion in an Aqueous Environment
Effect of (-Cyclodextrin Charge Type on the Molecular Recognition Thermodynamics of Reactions with (
A Facile Total Synthesis of Hainanensine via an Unusual Rearrangement-Annulation Cascade
Simply modified chiral diphosphine: catalyst recycling via non-covalent absorption on carbon nanotub
Molecular aggregation behavior of perylene-bridged bis((-cyclodextrin) and its electronic interactio
A Reversible Luminescent Lanthanide Switch Based on a Dibenzo[24]-Crown-8- Dipicolinic Acid Conjugat
Imidazolium-Based Macrocycles as Multisignaling Chemosensors for Anions
Quinolinotriazole-β-cyclodextrin and its adamantanecarboxylic acid complex as efficient water-solubl
A Highly Selective and Synthetically Facile Aqueous-Phase Cyanide Probe
Sulfonium alkylation followed by 'click' chemistry for facile surface modification of proteins and t
Cyanine Dye-Based Chromofluorescent Probe for Highly Sensitive and Selective Detection of Cyanide in
Reactions of dihydrooctamethyl-s-indacene and 1,2,3,4,7-pentamethylindene with Ru3(CO)12: Intramolec
Design, Synthesis and 3D-QSAR Analysis of Novel 1,3,4-Oxadiazol-2(3H)-ones as Protoporphyrinogen oxi
A colorimetric and "turn-on" fluorescent chemosensor for Zn(II) based on coumarin Shiff-base derivat
Efficient Construction of Oxa- and Aza-[n.2.1] Skeletons: Lewis Acid-Catalyzed Intramolecular [3+2]
Supramolecular assembly of perylene bisimide with β-cyclodextrin grafts as a solid-state fluorescenc
Magnetic Nanoparticle Supported Ionic Liquid Catalysts for CO2 Cycloaddition Reactions
Ferrocene-Based Imidazolium Receptors for Anions
Total Synthesis of (±)-Bruguierol A via an Intramolecular [3+2] Cycloaddition of Cyclopropane 1,1-Di
Organocatalytic Three-Component Reactions of Pyruvate, Aldehyde and Aniline by Hydrogen-Bonding Cata
Chiral Primary Amine–Polyoxometalate Acid Hybrids as Asymmetric Recoverable Iminium-Based Catalysts
Reactions of (Me2C)(Me2Si)[((5-C5H3)Mo(CO)3]2 with nitrile and subsequent cleavage of the C-N triple
Unexpected reactions of (Me2C)(Me2Si)[((5-C5H3)Mo(CO)3]2 with diazoalkane and carbon disulfide: Acti
Synthesis and reactivity of 2-(tert-butylcyclopentadienyl)-indenyl dinuclear ruthenium complex [?5:?
Hydride, Hydrogen Atom, Proton and Electron Transfer Driving Forces of Various Five-membered Heteroc
Supramolecular architectures of (-cyclodextrin-modified chitosan and pyrene derivatives mediated by
Enantioselective hydrogenation of (-aryloxy and (-alkoxy (,β-unsaturated carboxylic acids catalyzed
Access to B=S and B=Se double bond via sulfur and selenium insertion into a B-H bond and hydrogen mi
Enantioselective nickel-catalyzed reductive coupling of alkynes and imines
Enantioselective rhodium-catalyzed addition of arylboronic acids to ?-ketoesters
Enantioselective iron-catalyzed O–H bond insertions
Effective enlargement of fluorescence resonance energy transfer of poly-porphyrin mediated by β-cycl
Unique regioselective binding of permethylated β-cyclodextrin with azobenzene derivatives
Temperature-controlled supramolecular vesicles modulated by p-sulfonatocalix[5]arene with pPyrene
Highly selective fluorescent chemosensor for Na+ based on pyrene-modified calix[4]arene derivative
Homologous and heterologous interactions between catalytic and regulatory subunits of Escherichia co
Synthesis of Functionalized (-Cyclodextrins by “Click Chemistry”
Inclusion Complexation Behaviors of 3-Tigloyl-Azadirachtol With β-Cyclodextrin Derivatives
Noncovalent functionalization of single-walled carbon nanotube by porphyrin: dispersion of carbon na
Binding behaviors of scutellarin with (-, (-, (-cyclodextrins and their derivatives
Pyridyl-substituted indenyl ruthenium complexes: Synthesis, structures, and reactivities
Controlled/“living” radical polymerization of methyl methacrylate catalyzed by CpCo(I) complexes con
Chiral ruthenium-SDPs/diamine complexes-catalyzed enantioselective hydrogenation of (-alkyl arylacet
Bifunctional Catalysis of Morita-Baylis-Hillman (MBH) Reaction with Chiral Primary-Tertiary Diamine:
Unimolecular half-adders and half-subtractors based on acid-base reaction
Arginine Catalyzed Direct Aldol Reactions in Pure Water: An Environmentally Friendly Reaction System
Highly enantioselective and diastereoslective synthesis of chiral amino alcohols by ruthenium-cataly
Hot Water Promoted Ring-opening of Epoxides and Aziridines by Water and Other Nucleopliles
Asymmetric Direct Aldol Reactions of Acetoacetals Catalyzed by a Simple Chiral Primary Amine
Monomeric and Linear Polymeric Samarium(II) Complexes of the 2-(N-Arylimino)pyrrolide Ligand
Base-Stabilized 1-Silacyclopenta-2,4- dienylidenes
Solid-state supramolecular architectures by p-sulfonatocalix[5]arene with bispyridinium derivatives:
Synthesis of Thermostable Azo-type Photoswitches towards Photoregulating Nucleic Acid Structures
Fluorescene Switch of Tweezers-type Bis(zinc porphyrin) Complex Regulated by Double of Cu ion and DA
A Highly Sensitive Fluorescence Probe for Fast Thiol-Quantification Assay of Glutathione Reductase
Chiral Spiro Diphosphines
Reaction Control by Molecular Recognition – A Survey from the Photochemical Perspective (Chapter 1)
Enantioselective Hydrogenation of Enamines with Monodentate Phosphorus Ligands
咪唑修饰的卟啉化合物的合成及其对卤素离子的选择性识别
双（1-甲基咪唑-2-基）甲酮、双（1-甲基咪唑-2-基）甲烷及双（1-甲基咪唑-2-基）乙烯与第六族羰基金属化合物的反应研究
卟啉和酞菁修饰的单壁碳纳米管的合成及光谱性质
二茂铁-酞菁-富勒烯超分子三元体系的构筑及光物理和电化学性质
一种基于吡喃鎓离子的分子半加器和半减器研究
可溶性聚乙二醇负载的烟酰胺辅酶模型物设计合成及应用
Marcus电子转移理论的科学性探讨
有机锡2-[（1,2,4-三唑-1-基）甲基硫代]苯甲酸酯的合成与生物活性
卟啉-碳纳米管复合物研究进展