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长江三角洲地区典型废水中抗生素的初步分析
  • 期刊名称:环境化学,2008, 27(3): 371-373
  • 时间:0
  • 分类:X713.03[环境科学与工程—环境工程] S816.73[农业科学—饲料科学;农业科学—畜牧学;农业科学—畜牧兽医]
  • 作者机构:[1]同济大学环境科学与工程学院,长江水环境教育部重点实验室,上海 200092
  • 相关基金:国家自然科学基金基础项目(20777055).致谢:感谢上海市出入境检验检疫局动植物与食品检验中心对我们工作的支持.
  • 相关项目:环境暴露水平典型四环素类抗生素胚胎致畸效应与化学机制
中文摘要:

采用高效液相色谱-串联质谱方法,对城市生活污水、养猪场和甲鱼养殖场废水进行抗生素污染检测.污水处理厂污水中检出磺胺二甲嘧啶、磺胺甲氧嘧啶和磺胺甲恶唑3种磺胺类抗生素,浓度都低于5μg·l^-1.养猪场废水中检出磺胺甲恶唑、磺胺对甲氧嘧啶、磺胺嘧啶、磺胺二甲嘧啶和磺胺氯哒嗪5种磺胺类抗生素(〈5μg·l^-1),四环素类的四环素、土霉素和强力霉素(30.05—100.75μg·l^-1).甲鱼养殖场废水检出氯霉素、甲砜霉素和氟甲砜霉素3种氯霉素抗生素,浓度低于检测下限0.1μg·^l-1.结果表明,在3种典型废水中,养猪场废水检出抗生素的种类最多,浓度也最高;磺胺类在3种废水中检出频率最高,尤其是磺胺甲恶唑、磺胺二甲嘧啶和磺胺甲氧嘧啶.说明城市生活污水、畜禽养殖场废水和水产养殖废水都是水环境潜在的抗生素污染源.

英文摘要:

The occurrence of antibiotics in municipal wastewaters, swine manure wastewaters and turtle farm wastewaters were studied using high performance liquid chromatography-electrospray ionization tandem mass spectrometry. Results showed Sulpamonmethoxine, sulfamethoxydiazine and sulfamethoxazole were detected in municipal wastewaters with concentrations below 5 μg·l^-1. 5 sulfonamides(〈5 μg·l^-1)and 3 tetracyclines(30.05—100.75 μg·l^-1)were detected in swine manure wastewaters.In turtle farm wastewaters,3 chloramphenicols antibiotics(〈0.1 μg·l^-1)were found.Among 3 kinds wastewaters, swine manure wastewater had antibiotics of most kinds and highest concentrations.Tetracyclines were found having the highest concentrations.Sulfonamides, especially sulfamethoxazole, Sulpamonmethoxine and sulfamethoxydiazine, were detected most frequently.Therefore, 3 kinds wastewater were potential antibiotic pollution sources to aquatic environments in Changjiang delta.

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