在常规条件下合成了一种新型的氨基酸功能化的多金属氧酸盐化合物[(Gly)2(H2O)2Cu]K3[Al(OH)6Mo6O18]·7H2O,并通过元素分析、红外光谱、紫外可见光谱、热重分析和X射线单晶衍射等方法对其晶体结构进行了表征.结构分析表明:该晶体属于三斜晶系,Pi空间群,晶胞参数a=0.81053(16)nm,b=1.1394(2)nm,c=1.8247(4)nm,α=93.96(3)°,β=92.89(3)°,γ=108.90(3)°,V=1.5858(5)nm^3,Z=2.
A new amino acid functionalized polyoxometalate [(Gly)2(H2O)2Cu]K3[Al(OH)6Mo6O18]·7H2O ( 1 ) has been obtained in aqueous solution and characterized by IR, UV-Vis; element analysis, TG and single-crystal X ray analysis. The crystal data for compound 1 : Triclinic, space group Pi, a=0.81053(16)nm,b=1.1394(2)nm,c=1.8247(4)nm,α=93.96(3)°,β=92.89(3)°,γ=108.90(3)°,V=1.5858(5)nm^3,Z=2.