本文采用CVD法,以甩涂在衬底硅片上的Ga2O3薄膜和NH3作为原料,成功制备出大量GaN纳米线。采用X射线衍射仪(XRD)、场发射扫描电镜(FESEM)、能量色散谱仪(EDS)和高分辨透射电镜(HRTEM)对样品进行了成分和结构分析,并简单讨论了其生长机理。结果表明:产物为平直光滑的GaN纳米线,其直径为30nm-50nm。长度可达几十微米,纳米线为高质量的六方纤锌矿GaN晶体。
Large quantity GaN nanowires were synthesized via direct reaction of the films of Ga2O3 which were coated on the Si substrate with flowing ammonia. X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) equipped with an energy dispersive spec- trometer (EDS) and high resolution transmission electron microscope (HRTEM) were used to characterize the samples. The results show that: the products were straight and smooth GaN nanowires. Their diameters were in the range of 30nm - 50nm, lengths can be up to several microns. High quality GaN nanowires are obtained with hexagonal structure.