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水热条件下C-O-P键的形成
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O611.4[理学—无机化学;理学—化学]
  • 作者机构：[1]吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130012
  • 相关基金：国家自然科学基金（批准号：90922034,21131002,21201075）和高等学校博士学科点专项科研基金（批准号：20110061130005）资助.
作者： 王羽[1], 冯守华[1]
关键词： 水热环境, 生命起源, 磷酸甘油, C-O-P键, Hydrothermal environment, Origin of life, Glycerol phosphate, C-O-P bond
中文摘要：

利用水热反应模拟原始地球的水热环境,以甘油和磷酸二氢铵为原料,采用非生物手段合成了sn-甘油-1（3）-磷酸和甘油-2-磷酸2种磷酸酯类物质.通过此反应,无机磷进入生物分子形成了在生物体中起重要作用C-O-P键.研究了反应温度、反应时间及矿物催化剂对反应的影响.在蒙脱土的催化下,C-O-P键的产率最大可达到1.15%（摩尔分数）.

英文摘要：

Glycerol phosphates were abiotically synthesized under hydrothermally mimicked conditions with glycerol and ammonium dihydrogen phosphate. Inorganic phosphorus was therefore incorporated into biological molecule, leading to the formation of C-O-P bonds. Some factors affecting the yields of the products were taken into account. The best yield（ molar fraction） of C-O-P bonds through single-step hydrothermal syn-thesis is ca 1.15%.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:50676