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BOPP膜表面接枝聚己内酯的研究
  • ISSN号：1671-4628
  • 期刊名称：《北京化工大学学报：自然科学版》
  • 时间：0
  • 分类：O631.5[理学—高分子化学;理学—化学]
  • 作者机构：[1]北京化工大学材料科学与工程学院,北京100029
  • 相关基金：国家自然科学基金重点项目（50433040）;北京市教委高分子化学与物理学科建设项目（XK100100433/XK100100540）
作者： 隋圆[1], 赵京波[1], 杜小瑾[1], 杨万泰[1]
关键词： 聚丙烯, ε-己内酯, 异丙醇铝, 开环聚合, polypropene, ε-caprolactone, aluminum was obtained by the two-step method. isopropoxide, ring-openlng polymerization
中文摘要：

以异丙醇铝为催化剂，采用一步法和两步法在聚丙烯膜表面接枝聚己内酯。ATR-FTIR、XPS及表面水接触角测定分析证实了接枝反应的发生。采用一步法接枝可以得到平坦覆盖的接枝层，而用两步法接枝得到了细小颗粒分布的表面，膜表面氧与碳的摩尔比分别为0．167和0．141。接枝聚己内酯后，BOPP膜表面的水接触角由100°降低到82°。

英文摘要：

Ring-opening polymerization of ε-caprolactone （ε-CL） on the surface of hydroxylated biaxially oriented polypropylene （BOPP） film was initiated by aluminum isopropoxide in a sequential two-step method and in a one-step method. Attenuated total reflectance-Fourler transform infrared （ATR-FTIR） spectroscopy, X-ray photoelectron spectroscopy （XPS）, and contact angle measurements confirmed that the grafting reaction occurred successfully in both cases, and that the one-step method was more effective than the sequential two-step method. SEM results show that a flat surface with a grafted layer covering could be obtained by the one-step method, whilst a surface with a distribution of small particles was obtained by the two-step method.

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期刊信息
  • 《北京化工大学学报：自然科学版》
  • 北大核心期刊（2011版）
  • 主管单位:教育部
  • 主办单位:北京化工大学
  • 主编：刘振宇
  • 地址：北京市北三环东路15号
  • 邮编：100029
  • 邮箱：bhxbzr@126.com
  • 电话：010-64434926
  • 国际标准刊号：ISSN：1671-4628
  • 国内统一刊号：ISSN：11-4755/TQ
  • 邮发代号:82-657
  • 获奖情况:
  • 1999年教育部优秀科技期刊二等奖,1997年第二届全国科技期刊评比三等奖,1995年全国重点高校自然科学学报二等奖,中国期刊方阵“双效”期刊,首届高校优秀科技期刊,全国石化行业优秀期刊一等奖
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:9420