对中间相炭微球(MCMB)进行改性,以改性MCMB(M.MCMB)为基体、柠檬酸为碳源,由化学还原法、球磨法及热裂解工艺制得SnSbCu05/M—MCMB/C复合材料。用XRD、SEM及恒流充放电等方法研究样品、纯SnSbCu05合金和SnSbCu0.5/M.MCMB负极材料。SnSbCu0.5/M-MCMB/C复合材料可缓解纯SnSbCu0.5,合金的体积膨胀效应,提高循环稳定性。以100mA/g在0.01~2.00V循环,首次放电比容量为648.51mAh/g,库仑效率为74.55%,第80次循环的容量保持率为80.26%。
Mesocarbon microbead (MCMB) was modified. Via chemical reduction method, ball-milling method and thermal cracking method with modified MCMB (M-MCMB) as matrix and citric acid as carbon source, SnSbCuo.s/M-MCMB/C composite was synthesized. XRD, SEM and galvanostatic charge-discharge analyses were used to study the samples, pure SnSbCuo.5 and SnSbCu0.5/M-MCMB. SnSbCu0.5M-MCMB/C composite could reduce the volume expasnsion effect and improve the cycle stability. When cycled in 0. 01 -2. 00 V with 100 mA/g, the initial specific discharge capacity was 648. 51 mAh/g, the coulombic efficiency was 74. 55% ,the capacity retention in the 80th cycle was 80. 26%.