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在低频振动场中注塑成型iPP试样的结构与性能研究
  • ISSN号:1000-3304
  • 期刊名称:《高分子学报》
  • 时间:0
  • 分类:TQ320.662[化学工程—合成树脂塑料工业]
  • 作者机构:[1]重庆工学院材料科学与工程学院,重庆400050, [2]四川大学高分子科学与工程学院高分子材料工程国家重点实验室,成都610065
  • 相关基金:国家自然科学基金(基金号50473053,10590351)和重庆市科委(项目号CSTC,2006BB436)资助项目
中文摘要:

利用自行研制的低频振动注塑成型装置进行等规聚丙烯(iPP)试样的结构与性能研究.实验中对常规注射和振动注射成型的试样力学性能和微观形态进行了对比实验.采用低频振动注塑成型工艺实现了IPP试样的自增强,在190℃下进行注射,强度由常规试样的41.3MPa最大提高到振动试样的48.4MPa(振幅PA=59.4MPa,振频FR=0.7Hz),强度提高了17.2%;SEM显示常规试样芯层结构主要由球晶构成,振动注射使球晶在流动方向上变形、取向,晶粒尺寸得到细化;DSC表明振动注射促进熔融峰向高温漂移,晶体结晶更加完善,结晶度最大提高了12.1%;WAXD显示低频大振幅振动注塑有利于γ晶型的生成,γ晶型有利于试样实现自增强.

英文摘要:

A self-made low frequency vibration injection molding device was adopted to explore the mechanical properties and morphology for iPP injected moldings. The morphology and mechanical properties of samples produced by conventional injection molding (CIM) were used to compare with those obtained by vibration injection molding (VIM). For VIM the main processing parameters are vibration frequency and vibration pressure amplitude, the range of vibration frequency is 0 - 3 Hz, and the range of pressure vibration amplitude is 0 - 59.4 MPa. During the injection and pressure holding stages for CIM the injection and holding pressures are always constant, but for VIM an additional pulsing pressure vibration is exerted on the melt in the runner system and mold cavity, causing compression and decompression on the melt and shearing at the melt-solid interface, and it progresses from surface to core of the dumbbell specimen during solidification stage. In this work, the isotactic polypropylene material was plasticized and pumped into the melt chamber by a single screw extruder. During injection and pressure holding stages for the VIM,the melt was vibrated about 25 s in the dumbbell specimen mould and then cooled down in about 20 s. The melt injection temperature and mould temperature are set at 190℃ and 40℃ respectively. The injection pressure for CIM and the base pressure for VIM was 39.5 MPa.The VIM samples were injected at different vibration frequencies and pressure vibration amplitudes, respectively. To prepare VIM samples treated under different vibration frequencies,the vibration pressure amplitude was set at 19.8 MPa, and for VIM samples teated under different vibration pressure amplitudes, the vibration frequency was set at 0.7 Hz. With application of melt vibration technology the mechanical properties of iPP injection moldings were improved. The tensile strength and impact strength increase with the increasing of pressure vibration amplitude, while the elongation at break decreases. The tensile strength inc

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174