利用射频等离子体增强化学气相沉积(PECVD)技术低温制备了氢化纳米晶硅(nc-Si:H)薄膜.通过优化沉积参数,得到晶粒尺度小于10nm,晶态体积比为58%的nc-Si:H薄膜.对nc-Si:H薄膜的光电特性进行研究.结果表明,在i00mW/cmz的光照下,nc-Si:H薄膜的光电导率为1.5×10^-3Ω^-1·cm^-1,室温暗电导率为8.4×10^-4Ω^-1·cm^-1.光学带隙为1.46eV.利用射频PECVD制备的nc-Si:H薄膜具有明显的量子点特征.
Nanocrystalline silicon(nc-Si:H) films were deposited at low temperatures by radio friquency plasma enhanced chemical vapor deposition technique (PECVD). The nc-Si : H thin films with the crystal grain size of smaller than 10 nm and the crystal volume fraction X, of 58% were obtained by optimizing deposition parameters. The electrical and optical properties of the nc-Si: H films were investigated,and the results showed that the nc-Si: H films have a high photo-conductivity σp of 1.5^-3Ω^-1·cm^-1 under 100 mW/cm^2 illumination,a dark-conductivity σd of 8.4^-4Ω^-1·cm^-1 at room temperature and a optical band gap of 1.46 eV. The nc-Si: H films deposited by rf-PECVD evidently have the features of quantum dot.