在国内外重金属监测技术的基础上对环境污染事故中重金属(铜、铅、锌、砷、汞、铬、镉)的两种主要快速监测方法进行了研究。研究结果表明:比色法可测试铜、铅、锌、镉、六价铬5种重金属,且精密度与准确度均较好;阳极溶出伏安法(ASV)可测试铜、铅、锌、镉、砷、汞6种重金属,但测定六价铬时偏差较大;除六价铬和铜外,阳极溶出伏安法的测试范围较比色法宽,且检出限较低;阳极溶出伏安法可同时测定镉、铅、铜3种金属,具有较好的适用性。
Based on the monitoring technologies of heavy metals in the world,two major rapid methods for monitoring the heavy met-als(Cu,Pb,Zn,As,Hg,Cr and Cd)in environmental pollution accidents were studied in this paper.The results showed that:Col-orimentric method can test the content of Cu,Pb,Zn,Cd and Cr (VI),which reveals a good precision and accuracy;Anodic strip-ping voltammetry(ASV)can test the content of Cu,Pb,Zn,Cd,As and Hg,but has a large discrepancy when applied in testing Cr (VI);ASV has a larger test range and lower detection limit than colorimentric method with exception of Cu and Cr(VI);ASV can test the content of Cd,Pb and Cu simultaneously,which also displays a good applicability.