为了扩展胶体灭火剂应用范围,进一步提高灭火效率,采用相分离法合成了P(NIPA—CO-SA)温敏性高分子水凝胶.采用FT—IR傅里叶红外光谱、表面张力仪和黏度仪表征了产物结构、温敏性能及相关物理参数.根据GB17835--2008搭建了A类灭火实验台,并对比研究了水、普通胶体和温敏性水凝胶的灭火效果.结果表明:合成产物为目标产物P(NIPA-co-SA);环境温度超过临界相转变温度后,水凝胶发生体积相转变而凝胶化,表面张力低、黏度大;作为温度敏感性泡沫液最佳使用质量分数为0.39/6,能够有效扑救A类固体火灾,灭火效果优于水及普通胶体灭火剂.
In order to widen the application and enhance the fire extinguishing efficiency nary gel, a temperature-sensitive hydrogel P(NIPA-co-SA) was synthesized by phase of ordi- separa- tion. The product structure, temperature-sensitivity performance and relevant physical param- eters were characterized through Fourier transform infrared spectrometer, surface tensiometer and viscometer. According to national standard GB17835-2008, the solid combustible fire ex- periment rig was established, and the fire extinguishing performance of water, ordinary gel and temperature-sensitive hydrogel were comparatively studied. The results show that: synthesized product is target product P(NIPA-co-SA). Because of volume phase transition (VPT) hydrogel became gelled when temperature is above lower critical solution temperature (LCST), and the surface tension was low and viscosity was high. 0. 3% is the recommended concentration for temperature-sensitive firefighting foam preparation, which can effectively quench solid combus- tible fire. Its fire extinguishing performance is better than that of water and ordinary fire extin- guishing agent.