研制了石墨烯掺杂Cs2CO3(Cs2CO3:Graphene)作为高效电子注入层、结构为ITO/N,N′-bis-(1-naphthyl)-N,N′-diphenyl-1,1′-biphenyl-4,4′-diamine(NPB)(50nm)/tris-(8-hydroxy quinoline)-aluminum Alq3(80nm)/Cs2CO3:Graphene(mss 20%1nm)/Al(120nm)的OLEDs。将其与标准器件ITO/NPB(50nm)/Alq3(80nm)/LiF(0.5nm)/Al(120nm)作性能比较,研究石墨烯掺杂在Cs2CO3中作为电子注入层对OLEDs性能的影响。结果表明,基于Cs2CO3:Graphene结构作为电子注入层的器件效率要高于LiF作为电子注入层的器件,其最大电流效率达到2.02cd/A,是标准器件的2.59倍;亮度也高于LiF作为电子注入层的器件,在10V时达到最大值7 690cd/m2,是标准器件最大亮度的2.07倍。性能得到提高的主要机理是由于Cs2CO3:Graphene的引入提高了电子注入效率。
Highly efficient orgallic light-emitting diodes (OLEDs) are fabricated with a novel efficient e- lectron injection layer consisting of Csz CO3 : graphene. The structure of devices is ITO/N, N'-bis-(1- naphthyl)-N, N'-diphenyl- 1, l'-biphenyl-4,4'-diamine (NPB) (50 nm) / tris- (8-hydroxy quinoline)-alu- minum Alq3 (80 nm)/CszCOa :Graphene (20 wt.%1 nm)/Al(120 nm). The test results are compared with the standard device consisting of ITO/NPB(50 nm)/Alqs (80 nm)/LiF(0. 5 nm)/Al(120 nm),and the effect of Csz COs :graphene as electron injection layer on the OLEDs properties is studied. The re- sults show that the efficiency of the device based on Csz COa :graphene as an efficient electron injection layer is higher than that based on LiF as electron injection layer. The maximum current efficiency of the device reaches 2.02 cd/A at 9.5 V,which is 2.59 times of that of standard device;the maximum lumi- nance of this device reaches 7 690 cd/m2 at 12 V, which is 2.07 times of that of standai'd device. The performance of device with an electron injection layer consisting of Csz CO3 : graphene is improved, and the main reason is that it can enhance the electron electron injection.