中文摘要：

在HFCVD系统中施加栅极偏压和衬底偏压，采用双偏压成核和栅极偏压生长的方法成功制备了高质量的纳米金刚石薄膜。采用显微Raman高分辨率SEM和AFM等现代理化分析手段分析纳米金刚石膜的微结构，结果表明双偏压显著促进了金刚石的成核密度，平均晶粒尺寸在20nm以内。试验观察和理论分析表明栅极偏压促进了热丝附近的等离子体浓度，提高了衬底附近的碳氢基团和氢原子浓度，提高了金刚石的成核密度、在保持晶粒的纳米尺寸的同时保持了较高的成膜质量和较低的生长缺陷。

英文摘要：

A positive grid bias and a negative substrate bias voltages are applied to the self-made hot filament chemical vapor deposited （HFCVD） system. The high quality nanocrystalline diamond （NCD） film is successfully deposited by double bias voltage nucleation and grid bias voltage growth. The Micro-Raman XRD SEM and AFM are used to investigate the diamond grain size, microstructure, surface morphology, and nucleation density. Results show that the obtained NCD has grain size of about 20 nm. The effect of grid bias voltage on the nucleation and the diamond growth is studied. Experimental results and theoretical analysis show that the positive grid bias increases the plasma density near the hot filaments, enhances the diamond nucleation, keeps the nanometer size of the diamond grains, and improves the quality of diamond film.