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聚苯乙烯负载多吡啶铂（Ⅱ）配合物选择性检测Mg^2＋离子
  • ISSN号：1674-0475
  • 期刊名称：《影像科学与光化学》
  • 时间：0
  • 分类：O64[理学—物理化学;理学—化学]
  • 作者机构：[1]中国科学院理化技术研究所,光化学转换与功能材料重点实验室,北京100190, [2]中国科学院研究生院,北京100039, [3]西北大学化学与材料学院,合成与天然功能分子化学教育部重点实验室,西安710069
  • 相关基金：国家自然科学基金项目（20732007,20728506）;科技部国家重点基础研究发展规划项目（2006Ct3806105,2007CB808004,2007CB936001）;中科院基础局资助项目.
作者： 王登慧[1,2], 彭明丽[1,3], 佟振合[1], 吴骊珠[1]
关键词： 多吡啶铂(Ⅱ)配合物, 聚苯乙烯, Mg2+检测, 发光响应, ： polypyridyl platinum（ Ⅱ） complex, polystyrene , Mg^2 ＋ detection, luminescence sensor
中文摘要：

本文通过超声反应，将氮杂15-冠-5-苯乙炔引入聚苯乙烯负载多吡啶铂（Ⅱ）配合物．研究发现聚苯乙烯负载氮杂15-冠-5-苯乙炔基多吡啶铂（Ⅱ）配合物完全保持了单体多吡啶铂（Ⅱ）配合物的性质，并能够通过发光光谱的显著增强选择性地检测Mg^2＋离子．通过加入极性溶剂沉淀析出聚苯乙烯负载多吡啶铂（Ⅱ）配合物，从而达到分离的目的．

英文摘要：

N-15-monoazacrown-5-phenylacetylide was introduced to the polystyrene-supported polypyridyl platinum（Ⅱ） complex by ultrasonication in DMF. The obtained polystyrene-supported complex P1 can detect Mg^2 ＋ specifically both in solution color and luminescence intensity similar to that of the unbound mononuclear platinum（Ⅱ） complex M1. Moreover, the polystyrene-supported platinum（Ⅱ） acetylide complex could be separated simply by adding polar solvent for precipitation.

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期刊信息
  • 《影像科学与光化学》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院理化技术研究所 中国感光学会
  • 主编：佟振合
  • 地址：北京市海淀区中关村东路29号中国科学院理化技术研究所
  • 邮编：100190
  • 邮箱：xb@mail.ipc.ac.cn
  • 电话：010-82543683
  • 国际标准刊号：ISSN：1674-0475
  • 国内统一刊号：ISSN：11-5604/O6
  • 邮发代号:2-383
  • 获奖情况:
  • 中国科技核心期刊,《中文核心期刊要目总览》化学类核心期刊,全国优秀科技期刊二等奖",中国科学院优秀科技期刊一等奖,中国期刊方阵"双百期刊"
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:606