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氢键介质的折叠体连接的双香豆素衍生物：通过吸收和荧光光谱研究其溶剂效应
  • ISSN号：0023-074X
  • 期刊名称：《科学通报》
  • 时间：0
  • 分类：O626.31[理学—有机化学;理学—化学]
  • 作者机构：[1]河南化学研究所,郑州200032, [2]中国科学院上海有机化学研究所,生命有机化学国家重点实验室,上海200032
  • 相关基金：国家自然科学基金（20732007,20921091,20672137,20872167）、国家重点基础研究发展计划（2007CB808001）和上海市科学技术委员会（09XD1405300）资助项目
作者： 鲁郑全, 朱元元[2], 林建斌[2], 蒋锡夔[2], 黎占亭[2]
关键词： 香豆素衍生物, 溶剂效应, 荧光光谱, 氢键, 吸收, 连接, 折叠, 介质
中文摘要：

合成了3个芳酰胺桥连的双香豆素衍生物1～3（图1）.化合物1和2通过分子内N-H…O和N-H…F氢键诱导形成螺旋构象,而化合物3被N-H…O氢键诱导产生扩展构象.

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期刊信息
  • 《科学通报》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编：周光召
  • 地址：北京东黄城根北街16号
  • 邮编：100717
  • 邮箱：csb@scichina.org
  • 电话：010-64036120 64012686
  • 国际标准刊号：ISSN：0023-074X
  • 国内统一刊号：ISSN：11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
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  • 被引量:81792