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中文摘要：
本项目围绕有序分子聚集体组装及组装体中的光诱导能量传递、电子转移和化学转换开展研究，在以下几方面取得重要进展1）系统研究了氢键诱导的分子折叠体在超分子聚合物、凝胶、囊泡、液晶组装的应用，结合氢键结构预组织和动态共价键原理发展了一类高效及定量构筑大环体系的新方法；2）构筑若干四氢键超分子体系，证明分子间的远程能量传递和电子转移能够在自组装体系内通过氢键进行；3）利用氢键、配位作用和疏水作用为驱动力发展了一系列有序组装体，通过控制组装体内电子转移过程构筑了若干太阳能光催化制氢的新体系；4）以分子聚集体提供的纳微米空间为微反应器提高了多类化学反应的选择性，发展了提高光化学反应立体选择性的几个策略。上述结果在Acc. Chem. Res. (1篇)、Angew. Chem. Int. Ed. (2篇）、J. Am. Chem. Soc. (3篇)等刊物上发表论文83篇，培养博士研究生25名，1人获全国百篇优秀博士论文。
结论摘要：
英文主题词molecular aggregate; intermolecular interactions; molecular foldamer;energy transfer and electron transfer; microreactors;
成果综合统计
期刊论文
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期刊论文
Thieme Chemistry Journal Awardees - Where are They Now? Synthesis of p-Phenylene Ethynylene Based Ma
Chiral eighteen-component three-dimensional supramolecular entities stabilized by the hydrogen bondi
Vesicle Self-Assembly by Tetrathiafulvalene Derivatives in Both Polar and Nonpolar Solvents and Pseu
Two novel quadruple hydrogen-bonding motifs: the formation of supramolecular polymers, vesicles, and
Controllable self-assemblies of micro/nano-tubes and vesicles from arylamides and their applications
Hydrogen-Bonded Shape-Persistent Aryl Hydrazide Polymers: Side-Chain-Tuned Formation of Vesicles and
Self-Assembly of Vesicles by a 2,6-Di(7-benzamidy)quinolin-2-yl) pyridine Derivative Tuned by an Amp
Construction of Microbelts through the Coassembly of a Disclike Molecule and Primary Alkyl Ammoniums
Hydrogen bonded foldamer-bridged biscoumarins: A UV-Vis absorption and fluorescent study of the solv
Stepwise Photochemical-Chiral Delivery in gamma-Cyclodextrin-Directed Enantioselective Photocyclodim
Hydrogen bonded aryl amide and hydrazide oligomers: a new generation of preorganized soft frameworks
Silica- and polymer-supported platinum(II) polypyridyl complexes: synthesis and application in photo
Self-assembly of vesicles from the stacking of a dipodal F center dot center dot center dot H-N hydr
Complexes between hydrogen bonded bisporphyrin tweezers and cholesterol-appended fullerenes as organ
Intramolecular Six-Membered and Three-Center C-H center dot center dot center dot O Hydrogen Bonding
Hydrogen bonding-mediated foldamer-bridged zinc porphyrin-C(60) dyads: ideal face-to-face orientatio
Cholesterol-Appended Aromatic Imine Organogelators: A Case Study of Gelation-Driven Component Select
Complexation of two non-fully hydrogen bonded aromatic hydrazide heptamers toward n-octyl-alpha-L-gl
Intramolecular six-membered N-H center dot center dot center dot Br and N-H center dot center dot ce
Intramolecular N-H center dot center dot center dot O and N-H center dot center dot center dot N hyd
A click chemistry approach for the synthesis of macrocycles from aryl amide-based precursors directe
Colorimetric and electrochemical Pb(2+) detection by imine-bridged tetrathiafulvalene-pyridine deriv
meta-Substituted benzamide oligomers that complex mono-, di- and tricarboxylates: folding-induced se
Hydrogen Bonded Supramolecular Polymers in Both Apolar and Aqueous Media: Self-Assembly and Reversib
Tunable Coordinative Assembly of a Disc-Like Molecule and Metal Ions: From Mirospheres to Microtubes
Supramolecular complexation and photocyclodimerization of methyl 3-methoxy-2-naphthoate with modifie
Efficient and selective photodimerization of 2-naphthalenecarbonitrile mediated by cucurbit[8]uril i
Hydrogen-bonded aryl amide macrocycles: Synthesis, single-crystal structures, and stacking interacti
Hydrogen Bonding-Directed Quantitative Self-Assembly of Cyclotriveratrylene Capsules and Their Encap
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