为了探讨含碳耐火材料的导电性和渣渗透与组成的关系,采用w(C)=98%的石墨、纯度为99%(w)的富铝尖晶石为主要原料,以石墨添加质量分数分别为5%、10%、15%、20%、40%、60%的富铝尖晶石-碳试样研究了其导电性与组成的关系,以石墨添加质量分数分别为10%、20%、30%、35%、40%、60%、80%、100%的试样研究了其抗渣性与组成的关系。结果表明,富铝尖晶石-石墨试样的导电性及渣渗透性与组成的关系都符合逾渗模型,其导电性的逾渗阈值为14.3%(石墨的体积分数),而抗渣性的逾渗阈值为56.4%(尖晶石+孔隙的体积分数),且在逾渗阈值附近,材料的导电性对成型压力较为敏感。
Alumina-rich spinel-carbon specimens were prepared using graphite (C content is 98%,in mass,the same hereinafter)and alumina-rich spinel (the purity is 99%)as main starting materials to find the effects of composition on electric conductivity and slag-penetration of carbon containing refractories. The specimens with different graphite additions (5%,10%,15%,20%,40% and 60%)were used to ana-lyze relationship between electric conductivity and composition,and those with different graphite additions (10%,20%,30%,35%,40%,60%,80% and 100%)were used to analyze the relationship between slag-penetration and composition.It is found that two relationships can be described by percolation model;the percolation threshold of electric conductivity is 14.3%(volume fraction of graphite)and that of slag-pene-tration is 56.4% (volume fraction of spinel and pore),and the electric conductivity is sensible to shaping pressure when it nears the percolation threshold.