在丁腈橡胶(NBR)中添加受阻酚AO-60制备受阻酚/丁腈橡胶复合材料。利用DSC、SEM、动态力学分析仪(DMA)等测试手段对该复合材料的结构进行了表征,并研究了其动态力学性能。结果表明:AO-60在不同的NBR基体中的分散情况不同。在丙烯腈质量分数为35%的NBR基体(N230S)中,AO-60形成了精细的分散结构,且与NBR大分子之间形成了强烈的分子间作用力,两相相容性好。与纯NBR基体相比,AO-60/NBR复合材料的玻璃化转变温度(Tg)随着AO-60含量的增加逐渐升高,损耗因子(tanδ)逐渐增大,阻尼性能提高。同时,AO-60/N230S复合材料表现出更好的阻尼性能。
A hindered phenol/nitrile-butadiene rubber(NBR) composite was successfully prepared by mixing tetrakis(methylene-3-(3-5-ditert-butyl-4-hydroxy phenyl) propionyloxy) methane(AO-60) into NBR.The microstructure of the AO-60/NBR composite was characterized by DSC,SEM and DMA,and its dynamic mechanical properties were studied.The results show that the dispersion of AO-60 is different in the various NBR matrix.Hindered phenol AO-60 forms a fine dispersion in the matrix of the NBR with the acrylonitrile mass fraction of 35%(N230S).A strong intermolecular interaction is formed between the AO-60 and NBR.Compared with the neat NBR matrix,the value of Tg and tanδ for the composites increases gradually with increasing the AO-60 amount.Moreover,AO-60/N230S composites have a high performance as a damping material.