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HNBR胶液中铑金属催化剂脱除以及性能表征
  • 期刊名称：特种橡胶制品
  • 时间：0
  • 页码：18-22
  • 语言：中文
  • 分类：TQ333.7[化学工程—橡胶工业]
  • 作者机构：[1]北京化工大学新型高分子材料制备与加工重点实验室,北京100029, [2]北京化工大学碳纤维及功能高分子教育部重点实验室,北京100029
  • 相关基金：国家自然科学基金（20774009）; 国家教育部回国人员科研启动基金资助（LX2008-04）
  • 相关项目：橡胶（弹性体）
作者： 岳冬梅|张立群|周浩|李超|邢海琳|
关键词： 螯合树脂, 铑金属催化剂, 氢化丁腈橡胶, 力学性能, chelated resin, rhodium metal catalyst, HNBR, mechanical property
中文摘要：

研究了几种树脂对氢化丁腈橡胶二甲苯胶液中铑金属催化剂的吸附能力,考察了反应时间及树脂用量等条件对树脂吸附率的影响。结果表明,所得螯合树脂D418具有相对较好的吸附能力,对HNBR胶液中铑金属络合物吸附率可达到90%以上。通过GPC、傅里叶变换红外光谱、核磁共振波谱对脱除催化剂前后HNBR的相对分子质量以及结构进行了表征,同时对脱除催化剂前后的HNBR进行了力学性能测试。

英文摘要：

The adsorption ability of some kind of resins to the rhodium metal catalyst from hydrogenated nitrile rubber（HNBR） in dimethyl benzene was studied and the effect of reaction time,resin amount on the resin adsorption rate was observed.The results showed that chelated resin D418 exhibited good absorbing ability.The absorption rate of rhodium catalyst in HNBR solution was over 90%.The structure of HNBR before and after catalyst removal was characterized by IR and 1H-NMR.Also the mechanical properties of HNBR before and after catalyst removal was tested.

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橡胶（弹性体）
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