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聚乙二醇二丙烯酸酯/PVDF-HFP凝胶电解质膜的制备、结构与性能研究
  • 期刊名称：云南大学学报（自然科学版）， 5A: 377-379, 2005，
  • 时间：0
  • 分类：TM912[电气工程—电力电子与电力传动]
  • 作者机构：浙江大学高分子科学研究所, 浙江大学高分子科学研究所 浙江杭州310027, 浙江杭州310027
  • 相关基金：国家自然科学基金资助项目(50433010)
  • 相关项目：聚合物纤维和薄膜制备中多层次结构控制的研究
关键词： 凝胶聚合物电解质膜, 聚乙二醇二丙烯酸酯, 交联, 离子电导率
中文摘要：

采用低分子量聚乙二醇二丙烯酸酯(PEO-DA)与偏氟乙烯-六氟丙烯共聚物(PVDF-HFP)及锂盐电解液共混、过氧化苯甲酰(BPO)热引发自由基聚合,研究了具有交联网络结构的凝胶聚合物电解质膜(GPE)的制备.用衰减全反射红外光谱(FT-IR/ATR)表征了PEGDA中双键的交联反应;X-射线衍射(XRD)法表征了凝胶聚合物电解质的晶态结构.利用交流阻抗技术测定了GPE膜导电性,发现在室温下GPE膜的电导率达到1.655 mS/cm.

同期刊论文项目
聚合物纤维和薄膜制备中多层次结构控制的研究
期刊论文 115 会议论文 42 著作 1
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