采用硅胶、Sephades LH-20、RP-18等色谱技术,对草鞋木(Macaranga henryi)枝条中的化学成分进行了研究,共分离得到8个化合物,通过NMR、MS等波谱学技术将其结构分别鉴定为:12-O-tetradecanoylphorbol-13-acetate(1),trigowiin A(2),daturadiol(3),山楂酸甲酯(4),3β-羟基豆甾-5-烯-7-酮(5),3β-羟基豆甾-5,22-二烯-7-酮(6),豆甾-3,5-二烯-7-酮(7),丁香脂素(8)。化合物5为首次从该种植物中分离得到,其余化合物均为首次从该属植物中分离得到。
Eight compounds were isolated from the twigs of Macaranga twnryi by repeated column chromatography over silica gel,Sephadex LH-20 and RP-18. On the basis of NMR and MS spectroscopic analysis,their structures were identi- fied as 12-O-tetradccanoylphorbol-β-acetate (1) ,trlgowiin A (2) ,daturadiol (3) ,methyl maslinate (4) ,3β-hydroxy- stigmast-5 -en-7-one ( 5 ), 3β-hydroxystigmast -5,22-dien-7 -one ( 6 ), stigmasta-3,5-dien-7 -one ( 7 ), syringaresinol ( S ), respective])'. Compound 5 was isolated from this plant for the first time and all the other compounds were obtained from this genus for the first time.