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中文摘要：
手性Pd（Ⅱ）／P—PHOS（S）催化的丙烯／CO交替聚酮通过还原合成了一类新型手性聚多元醇．考察了4种还原剂LiAlH4，NaBH4，BH3·THF和Pd／C加氢对该聚酮的还原作用，其中LiAlH4和NaBH4可将聚酮分子链中羰基完全还原，生成手性交替聚多元醇，BH3·THF只能部分还原聚酮羰基，而Pd／C加氢对聚酮没有还原作用．
英文摘要：
A kind of novel chiral polyalcohols were synthesized by reducing chiral polyketones, which were prepared by alternating copolymerization of propene with CO catalyzed by chiral Pd （Ⅱ）/P-PHOS （S） complex. In the reduction process, LiAlH4, NaBH4, BH3 THF, and Pd/C catalytic hydrogenation were applied as reducing agents, respectively. When LiAlH4 or NaBH4 were used as reductants, keto-carbonyls in polyketone molecule were completely reduced to alcoholic hydroxyls, generating a novel chiral alternating polyalcohol smoothly. In the presence of BH3 THF, both keto-carbonyls and alcoholic hydroxyls were detected in products due to the partially reduction of polyketones, However, Pd/C catalytic hydrogenation of ployketones gave no desired products.
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