以聚乙烯醇(PVA)为高分子胶体稳定剂,以水溶性环氧树脂(WEP)为交联剂,采用无皂种子聚合制备了无皂苯丙共聚物乳液/水溶性环氧树脂复合表面施胶剂。以质量分数为2.5%的复合表面施胶剂进行表面施胶时,纸张施胶度可达13.6s、表面强度达3.4m/s、抗张强度达43N/m、耐折度达46次。
The heat-reactive surfactant-free polyacrylate/epoxysiloxane emulsion as surface size was prepared by the seed copolymerizatian, using polyvinyl alcohol (PVA) as dispersing agent, water-soluble epoxy resin as the crossliking agent. The factors affecting the synthesis were investigated and the optimum reaction conditions were described as below: seed polymerization, temperature 85℃, time 3.5 h, w(MAA) = 8% - 10%, n (BA)/n(St) = 1- 1.2,w (PVA)= 4%, w(WEP) = 2% .The paper treated with the diluted resultant emulsion with 2.5% solid content (mass fraction) obtained good properties, the sizing value was more than 13.6 seconds, the surfacee strength, tensile strength and folding endurance were 3.4m/s ,43N and 46 times respectively. The observation of SEM showed that the fibers and fines were well bonded together and formed a compact structure.