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羧甲基纤维素增强膜的制备及性能
  • ISSN号:1001-3563
  • 期刊名称:《包装工程》
  • 时间:0
  • 分类:TB484.6[一般工业技术—包装工程]
  • 作者机构:齐齐哈尔大学,齐齐哈尔161006
  • 相关基金:黑龙江省教育厅基本业务专项(135109305); 大学生创新创业训练计划(201710221132); 齐齐哈尔大学教研青年项目(2015063)
中文摘要:

目的为了获得一种可用于食品包装的羧甲基纤维素增强膜。方法以羧甲基纤维素(CMC)为成膜基底,甘油为增塑剂,分别将质量分数为1%,3%,5%和10%的纳米纤维素(NCC)添加到CMC中,共混流延制备羧甲基纤维素增强膜(CMC-NCC)。结果 NCC的加入,提高了CMC的力学性能和对水蒸气的阻隔性能,还提高了CMC的热性能。FT-IR分析结果表明,CMC与NCC两者间形成了分子间氢键;XRD分析结果表明,NCC可以改变CMC的结晶排列。当添加质量分数为5%的NCC时,CMC-NCC的拉伸强度比纯CMC膜提高了25.6%,断裂伸长率降低了21.3%,透湿量降低了9%,热稳定性提高了2%,透光率维持在87%以上。结论 CMC增强膜具有力学性能高、阻湿性能好等优点,NCC提高了CMC的成膜品质。

英文摘要:

The work aims to obtain the reinforced carboxymethyl cellulose films(CMC-NCC) for food packaging. With the carboxymethyl cellulose as the formed film base and the glycerol as the plasticizer, NCCs of 1%, 3%, 5% and 10% mass fraction were added into CMC by solution casting and then the CMC-NCC was prepared. The mechanical, moisture barrier and thermal properties of CMC were improved by incorporating the NCC. FT-IR analysis results proved that the intermolecular hydrogen bond was formed between CMC and NCC. XRD analysis results proved that NCC could change the crystallization arrangement of CMC. With the addition of 5% NCC, the tensile strength was increased by 25.6%, the elongation at break was decreased by 21.3%, the water vapor permeability was decreased by 9%, the thermal stability was improved by 2% and the light transmittance remained above 87%, compared to the pure CMC films. In conclusion, the reinforced CMC film is featured by high mechanical property, good moisture barrier property and other advantages, and NCC has improved the quality of the formed CMC films.

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期刊信息
  • 《包装工程》
  • 北大核心期刊(2011版)
  • 主管单位:中国兵器装备集团公司
  • 主办单位:中国兵器工业第五九研究所
  • 主编:吴护林
  • 地址:重庆市九龙坡区石桥铺渝州路33号
  • 邮编:400039
  • 邮箱:designartj@126.com
  • 电话:023-68792836
  • 国际标准刊号:ISSN:1001-3563
  • 国内统一刊号:ISSN:50-1094/TB
  • 邮发代号:78-30
  • 获奖情况:
  • 连续三届中文核心期刊,中国兵器工业总公司优秀期刊,重庆市质量优秀期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:26057