在微波辅助下用等体积的CS2-丙酮为溶剂对锡林浩特褐煤进行萃取,萃取物用GC/MS分析.结果表明:萃取物中共检测到70种有机化合物,可分类为烷烃、烯烃、芳烃、酚类、醛类、酮类、脂肪酸、酯类和含氮化合物.含氮化合物含量和种类均为最多,共26种含氮化合物,相对含量为54.36%,推测因为CS2和丙酮之间存在缔合关系,促使含氮化合物从煤中被萃取出来.
Xilinhaote lignite (XL) has been extracted using CS2/acetone (1 : 1 in volume) mixed solvent under microwave irradiation (MI). The extractable fraction is analyzed with gas chromatography/mass spectrometry (GC/MS). 70 compounds are identified from extractable fraction, and they can be classified into 9 groups components: alkanes, alkenes, arenes, phenols, aldehydes, ketones, fatty acids, esters and organonitrogen compounds (ONCs). The ONCs is the most abundant compounds whose relative content is 54.36%, and there are 26 ONCs detected in the extractable fraction. CS2 and acetone have π-π interaction to promote the extraction yield of ONCs from coal.