利用激光冷却俘获技术在双暗磁光阱中获得高密度的超冷铷原子和铯原子, 通过光缔合方法制备超冷铷铯极性分子. 采用共振增强双光子电离技术探测基三重态a3∑+的铷铯分子, 产率约为104/s. 通过改变缔合光频率, 获得(2)0+, (3)0-, (2)0-等分子态的高分辨振转光谱, 拟合得到相应的转动常数分别为0.00349 cm-1, 0.00649 cm-1, 0.00372 cm-1.
Ultracold polar RbCs molecules are produced via photoassociation in a dual dark-SPOT magneto-optical trap, in which ultracold rubidium and cesium atoms with high densities are formed by laser cooling and trapping. The a3∑+ triplet metastable state ultracold RbCs molecules with 104/s production rate are detected using resonance-enhanced two-photon ionization. The ultra-high resolution rovibrational spectra of (2)0+, (3)0- and (2)0- rovibrational states are observed by scanning the photoassociation laser frequency. The rotational constants of (2)0+, (3)0- and (2)0- vibrational states are 0.00349 cm-1, 0.00649 cm-1 and 0.00372 cm-1 by fitting respectively.