采用两种粒径的氧化铜粉末和粒径为1.5μm的三氧化钨粉末来制备高纯度的CuWO4粉末,分别通过控制CuWO4粉末在360和750℃两个阶段的氢气还原作用,制备出钨包覆铜纳米复合粉体。复合粉体的微观形貌,组织结构与颗粒尺寸采用扫描电子显微镜(SEM),X线衍射分析仪(XRD)和透射电子显微镜(TEM)进行测试,激光粒度测试仪(LPSA)用来测试CuWO4粉末的粒度。由小粒度CuWO4粉末制备出的钨包覆铜纳米复合粉体的钨包覆层厚度小,氢气还原制备的钨包覆铜复合粉体的平均粒径约50nm。
Two kinds of copper oxide with different particle sizes and 1.5 μm tungsten trioxide powder were employed to prepare the high-purity CuWO4 powder. By two stage hydrogen-reduction of the CuWO4 at 360 and 750 respectively and continuously, nano-composite powder of tungsten coated copper was synthesized. Micro-morphology, crystallization-components and grain-size of the products were investigated by scanning electron microscope (SEM), X-ray diffract meter (XRD) and transmission electric microscope (TEM) and laser particle size analyzer (LPSA) was also applied to measure the particle-size of CuWO4 . The W film thickness of nano-composite powder synthesized by smaller-sized CuWO4 is thinner than that made from bigger-sized CuWO4 . The average particle size of nano-composite powder of tungsten coated copper is about 50 nm under the two-stage hydrogen reduction.