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Iron-catalyzed transformations of diazo compounds
  • 期刊名称:National Science Review
  • 时间:2014.10.9
  • 页码:580-603
  • 分类:O643.36[理学—物理化学;理学—化学]
  • 作者机构:State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
  • 相关基金:supported by the National Natural Science Foundation of China and the National Basic Research Program of China(2012CB821600);the‘111’project(B06005)of the Ministry of Education of China;the Program for New Century Excellent Talents in University(NCET-10-0516)
  • 相关项目:杂原子有机化学
中文摘要:

Although iron-promoted diazo transformations were only discovered during the 1990s,iron can undergo facile changes in its oxidation state and possesses distinct Lewis acid character,and these properties have aforded iron a privileged position as a catalyst in the transformations of diazo compounds.In this review,we have provided an overview of the iron-catalyzed diazo transformation reactions reported in the literature by the end of 2013 with the aim of stimulating further interest in this area of research.

英文摘要:

Although iron-promoted diazo transformations were only discovered during the 1990s, iron can undergo facile changes in its oxidation state and possesses distinct Lewis acid character, and these properties have afforded iron a privileged position as a catalyst in the transformations of diazo compounds. In this review, we have provided an overview of the iron-catalyzed diazo transformation reactions reported in the literature by the end of 2013 with the aim of stimulating further interest in this area of research.

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